Attractive and repulsive interactions in the inelastic scattering of NO by Ar: A comparison between classical trajectory and close-coupling quantum mechanical results

Abstract

The rotationally inelastic scattering of NO by Ar was studied on a potential energy surface at the collision energy of a high resolution experiment. The study entailed the calculationm of the state-resolved integral and differential cross sections for all the excited levels of NO in the lowest spin-orbit manifold. The quasiclassical approach was shown to satisfactorily reproduce few observations seen in both the experimental and quantum mechanical state-resolved differential cross-sections. © 2003 American Institute of Physics ; Funded by the Ministry of Science and Technology of Spain under Grants No. BQU2002-04627-C02 and No. REN 2000-1557, by the European Union through the RTN Reaction Dynamics ~HPRN-CT-1999-0007!, and by the U.S. National Science Foundation ~Grant No. CHE-9971810! The research was performed within the Unidad Asociada ''Química Física Molecular'' between the Universidad Complutense and the CSIC. ; Peer Reviewed