Multivariate factorial analysis to design a robust batch leaching test to assess the volcanic ash geochemical hazard

Abstract

A method to obtain robust information on short term leaching behaviour of volcanic ashes has been developed independently on the sample age. A mixed factorial design (MFD) was employed as a multivariate strategy for the evaluation of the effects of selected control factors and their interactions (amount of sample (A), contact time (B), and liquid to solid ratio or L/S (C)) on the leaching process of selected metals (Na, K, Mg, Ca, Si, Al, V, Mn, Fe, and Co) and anions (Cl - and SO 4 2-). Box plots of the data acquired were used to evaluate the reproducibility achieved at different experimental conditions. Both the amount of sample (A) and leaching time (B) had a significant effect on the element stripping whereas the L/S ratio influenced only few elements. The lowest dispersion values have been observed when 1.0g was leached with an L/S ratio equal to 10, shaking during 4h. The entire method is completed within few hours, and it is simple, feasible and reliable in laboratory conditions. © 2012 Elsevier B.V. ; This study was carried out in the framework of the PEGEFA Working Group (Catalonian Government "Grup de Recerca Consolidat" 2009-SGR-972), and was partly funded by the Project ASH of the Spanish Ministry of Science and Technology (CGL2008-00099) and the FPU Grant of the Spanish Ministry of Education of one of the authors (F. Ruggieri, Ref. AP2006-04592). ; Peer Reviewed