ZSM-5/SBA-15 versus Al-SBA-15 as supports for the hydrocracking/hydroisomerization of alkanes

Abstract

[EN] Al-SBA-15 and ZSM-5/SBA-15 (ZSC) composite were synthesized following hydrothermal procedures in the presence of triblock copolymer Poly(ethylene glycol)- poly(propylene glycol)-poly(ethylene glycol) (Pluronic P123) and a mixture of tetrapropylammonium bromide (TPABr)/Pluronic P123 templates, respectively. Pt (0.5 wt.%)/Al-SBA-15 and ZSC bifunctional catalysts were then prepared by a wet impregnation methodology and investigated in the hydrocracking/hydroisomerization of n-decane. Pt/ZSC, containing a trimodal porous texture and high Bronsted acidity, exhibited hydrocracking activity while Pt/Al-SBA-15, showing merely Lewis acidity, was active for hydroisomerization. At 300 degrees C the conversion of n-decane on Pt/ZSC reached 98% and cracking selectivity was about 99%. Both catalysts were exhaustively characterized. ; This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grant number 104.05-2014.21. CM aknowledges financial support by the Spanish Government-MINECO through "Severo Ochoa" (SEV 2012-0267) and CTQ2015-70126-R. ; Huyen, PT.; Nam, LTH.; Vinh, TQ.; Martínez, C.; Parvulescu, VI. (2018). ZSM-5/SBA-15 versus Al-SBA-15 as supports for the hydrocracking/hydroisomerization of alkanes. Catalysis Today. 306:121-127. https://doi.org/10.1016/j.cattod.2017.03.040 ; S ; 121 ; 127 ; 306