Interactions dipolaires dans les solutions

In: Bulletin de la Classe des sciences, Band 41, Heft 1, S. 1242-1255

Abstract

The effect of small dipolar interactions in solutions is examined. Prigogine, Bellemans and Englert's theory of solutions is applied quite generally to interpret this effect in solutions of molecules of different sizes and different central interactions. Pure dipolar interactions and inductive forces in binary solutions containing one polar constituent are discussed. The theory is in good agreement with experimental data on the excess functions of the system CHCl3 — CCl4.