Suchergebnisse

Trabajo presentado al Young Researchers CIS, celebrado online del 6 al 8 de septiembre de 2021. ; Financial support from the Research Projects PID2019-104009RB-I00/AEI/10.13039/501100011033 and the Aragón Government (T43-20R) are gratefully acknowledged. ; Peer reviewed

The use of hydrogen as an energy vector leads to the development of materials with high hydrogen adsorption capacity. In this work, a new layered stannosilicate, UZAR-S3, is synthesized and delaminated, producing UZAR-S4. UZAR-S3, with the empirical formula Na4SnSi5O14·3.5H2O and lamellar morphology, is a layered stannosilicate built from SnO6 and SiO4 polyhedra. The delamination process used here comprises three stages: protonation with acetic acid, swelling with nonylamine and the delamination itself with an HCl/H2O/ethanol solution. UZAR-S4 is composed of sheets a few nanometers thick with a high aspect ratio and a surface area of 236 m2/g, twenty times higher than that of UZAR-S3. At −196 °C for UZAR-S4, H2 adsorption reached remarkable values of 3.7 and 4.2 wt% for 10 and 40 bar, respectively, the latter value giving a high volumetric H2 storage capacity of 26.2 g of H2/L. ; Financial support from the Spanish Ministerio de Economía y Competitividad (MINECO) is gratefully acknowledged through projects with grant numbers: MAT2010-15870, CTQ2012-31229 and CTQ2012-31762, as well as from the Fondo Europeo de Desarrollo Regional (FEDER), Regional Government of Aragón (DGA) and the European Social Fund (ESF). A. Berenguer-Murcia and C. Casado-Coterillo thank the MINECO for Ramón y Cajal fellowships (RyC 2009-03913 at the University of Alicante and RYC-2011-08550 at the University of Cantabria).

Resumen del trabajo presentado a la XXXVII Reunión Bienal de la Real Sociedad Española de Química, celebrada en Donostia-San Sebastián del 26 al 30 de mayo de 2019. ; Financial support from the Spanish Ministry of Economy and Competitiveness (MINECO) and European Regional Development Fund (MAT2016-77290-R), ESF and the Aragón Government (T43-17R) is gratefully acknowledged. ; Peer reviewed