Combined Kinetic Response of Two Substrates with Similar Reactive Patterns
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 62, Heft 1, S. 19-33
ISSN: 2065-9520
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In: Studia Universitatis Babeş-Bolyai. Chemia, Band 62, Heft 1, S. 19-33
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 62, Heft 2, S. 19-31
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 66, Heft 3, S. 107-121
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 65, Heft 3, S. 171-179
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 68, Heft 2, S. 37-51
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 65, Heft 1, S. 137-148
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 66, Heft 3, S. 141-160
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 62, Heft 2, S. 167-178
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 65, Heft 2, S. 45-56
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 62, Heft 4, S. 67-80
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 64, Heft 2 T1, S. 197-206
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 62, Heft 4, S. 193-199
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 66, Heft 3, S. 175-185
ISSN: 2065-9520
In: Studia Universitatis Babeş-Bolyai. Chemia, Band 68, Heft 2, S. 185-192
ISSN: 2065-9520
In: Revue roumaine de chimie: Romanian journal of chemistry, Band 68, Heft 5-6, S. 209-215
Organobismuth chalcogenides of type [CH3OCH2CH2N(CH2C6H4)2Bi]2E [E = S (1), Se (2)], containing two butterfly-like tetrahydro-dibenzo[c,f][1,5]azabismocine heterocyclic frameworks, were prepared and their solution behavior was investigated by multinuclear NMR spectroscopy (1H, 13C and 77Se, as appropriate) and mass spectrometry. Crystals of [CH3OCH2CH2N(CH2C6H4)2BiO]2SeO (3) were serendipitously formed during the synthesis of compound 2. The molecular structure of 3 was determined by single-crystal X-ray diffraction and revealed, besides a strong transannular N→Bi interaction, an additional O‧‧‧Bi interaction involving the oxygen of the NCH2CH2OCH3 pendant arm from the organic fragment attached to the metal atom, thus resulting in a 12Bi5 hypercoordinate species.