Suchergebnisse

AbstractInordinate levels of heavy metals in water sources have long been a matter of concern, posing serious environmental and public health risks. Adsorption, on the other hand, is a viable technique for removing heavy metals from water due to its high efficiency, low cost, and ease of operation. Blast furnace slag (BFS) is considered a cheap sorbent for the get rid of Co2+ and Pb2+ ions from aqueous media. The nonmodified slag is characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), N2 adsorption–desorption isotherms, energy dispersive X-ray analysis (EDX), scanning electron microscopy (SEM), and zeta potential. The removal of Co2+ and Pb2+ ions was carried out using batch adsorption experiments from an aqueous medium. The influence of several variables as pH, contact time, adsorbent dose, temperature, and initial ions concentration was considered. The isotherm, kinetic, thermodynamic, and recyclability were also conducted. The maximum uptake capacity for Co2+ and Pb2+ was 43.8 and 30.2 mg g−1 achieved at pH 6 after 60 min contact time. The adsorption kinetics and isotherms of BFS for Co2+ and Pb2+ fitted well to Avrami and Freundlich models, respectively. The main adsorption mechanism between BFS and the metal ions was ion exchange. The regeneration of the used slag was studied for reuse many cycles. In terms of economics and scalability, nonmodified BFS treatment has great potential as a cost-effective adsorbent that could be used in water pollution treatment.
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AbstractWaste printed circuit boards (WPCBs) contain a plethora of valuable metals, considered an attractive secondary resource. In the current research, a hydrometallurgical process combined ammonia/ammonium chloride leaching and reduction (using L-ascorbic acid) to recover copper and its oxide (CuO) as nanosized particles from WPCBs was investigated. The results of leaching indicated that 96.7% of copper could be recovered at a temperature of 35 °C for a leaching duration of 2 h with ammonium chloride and ammonia concentration of 2 mol/L at a solid:liquid ratio of 1:10 g/cm3. The synthesized particles exhibit spherical and distorted sphere morphology with average particle size of 460 nm and 50 nm for Cu and CuO NPs, respectively. The antibacterial activity of Cu, CuO, and a (1:1) blend of both (Cu/CuO) has been examined against five different bacterial and fungal strains. The highest zone of inhibition was measured as 21.2 mm for Cu NPs toward Escherichia coli and 16.7 mm for Cu/CuO blend toward Bacillus cereus bacteria. The highest zone of inhibition was measured as 13 mm and 13.8 mm for Cu/CuO blend toward Fusarium proliferatum and Penicillium verrucosum fungi. Cu/CuO blend showed notable photocatalytic activity towards Rhodamine B dye under visible light irradiation with 96% degradation rate within 120 min. Using the process developed in this study, copper and its oxide as nanoparticles can be produced from WPCBs and used for multifunctional applications.
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