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PROCEEDINGS, GEOFLUIDS VII ¿ International Conference IFP Energies nouvelles, Rueil-Malmaison (France), June 6-8, 2012 ; The Vilobí Gypsum Unit (upper Burdigalian) is located in the Penedès Half-graben (northeast of the Iberian Peninsula). This unit consists of a succession of secondary (predominant, coming from hydration of anhydrite) and primary (limited to the top interval) laminated-to-banded gypsum and laminated lutites-carbonates. This succession is affected by 5 fractures sets due to the fragile deformation related to the Neogene extensional stages recorded in the region. These fragile structures are partly or totally cemented by four gypsum cements types (fibrous, millimetrical crystals, aligned and macrocrystalline gypsum), resulting from fluid circulation along the fractures. A successive isotopic enrichment (¿34SVCDT, ¿18OVSMOW) from the host-gypsum rocks and the different fracture infillings is evidenced, thus suggesting chemical recycling processes. The strontium ratios of gypsum cements suggest higher fluid interaction during the macrocrystalline cements precipitation, with respect to the fibrous infillings. ; Financial support by the I+D+I Spanish Government research projects CGL2010-18260, CGL2009-11096 and Grup Consolidat de Recerca "Geologia Sedimentària" (2009 SGR-1458).

The upper Burdigalian Vilobí Gypsum Unit, located in the Vallès Penedès half-grabben (NE Spain), consists of a 60-m thick succession of laminated-to-banded secondary and primary gypsum affected by Neogene extension in the western part of Mediterranean Sea. This Tertiary extensional event is recorded in the evaporitic unit as six fracture sets (faults and joints), which can be linked with basin-scale deformation stages. All fractures are totally or partially infilled by four types of new gypsum precipitates showing a large variety of textures and microstructures. A structural and petrological study of the unit allows us to establish the following chronology of the fracture formation and infilling processes, from oldest to youngest: (i) S1 and S2 normal faults sets formation and precipitation of sigmoidal gypsum fibres; (ii) S3 joint set formation and growing of perpendicular fibres; (iii) S4 inverse fault development, infilled by oblique gypsum fibres and deformation of the previous fillings; and (iv) S5 and S6 joint formations and later dissolution processes, infilled by macrocrystalline gypsum cements. The fractures provided the pathway for fluid circulation in the Vilobí Unit. The oxygen, sulphur and strontium isotope compositions of the host rocks and the new precipitates in the fractures suggest clear convective recycling processes from the host-sulphates to the fracture infillings, recorded by a general enrichment trend to heavier S-O isotopes, from the oldest precipitates (sigmoidal fibres) to the youngest (macrocrystalline cements) and to the preservation of the strontium signals in the infillings. © 2013 Blackwell Publishing Ltd. ; The present work was supported by the Spanish Government Projects CGL2009-11096 and CGL2010-18260, and the Grup Consolidat de Recerca Geologia Sedimentaria (Catalan Government) 2009SGR-1451 ; Peer Reviewed