Suchergebnisse

The present study aims to assess the water quality and the hydrochemical characteristics and seasonal variation of surface water on the aspect of trace elements in Al-Tarmiyah District, Baghdad, Iraq. Ten water samples were collected, four from surface water and six from groundwater on October 2017, and on April 2018. All samples were analyzed for physiochemical parameters such as water temperature, pH, EC, TDS,TH,TSS, major ions (Ca2+, Mg2+, Na+, K+, SO42-, Cl-, and HCO3-), and nutrients (NO3-, and PO43-). In addition, samples were analyzed for trace elements that include Fe, Al, Pb, Zn, Mn, Cr, Cu, Co, Ni, and Cd. Suitability of water for domestic uses was evaluated depending on the criteria or standards of acceptable quality for that use.
Surface water samples of October 2017 were classified as Ca-Cl and Na-Cl water type while they were classified as Na-Cl water type in April 2018. Most groundwater of both months' samples was classified as Ca-Cl and Na-Cl water types. There is only one groundwater sample (GW2) was classified as Ca-SO4-2 water type. According to water classification based on the Piper diagram, most of surface and groundwater samples for both months falling in class (e), this means that the type of water is "Earth alkaline water with increased portions of alkalis with prevailing sulfate or chloride". Suitability of water for drinking purpose is evaluated depending on the criteria or standards of acceptable quality for that use ( WHO and Iraqi Standard). All surface and groundwater samples from the studied area are not suitable for drinking purposes and within "excellent type" for livestock and poultry use. Additionally, almost all surface water samples were within Good class based on the suggested limits of EC value (Ayers and Westcot, 1985) for irrigation while most of the groundwater samples are within unsuitable class. All surface water and groundwater samples lie within low hazard class of the irrigation water based on SAR values.

Heavy metals concentration in the soils and sediments has increased worldwide during the last century as a result of the rapid increase in population which combined by an increase in human activity as agriculture, industrial and many other activities. Ten soil and three river sediment samples were collected from 10 main sampling stations at Shatt Al-Hilla River from Sada area to Dora Bridge in Babylon province. The chemical analysis of the sedimentation sample in the laboratory included pH calculation, electrical conductivity (EC) (Cation Exchange Capacity (CEC), organic matter (OM), and heavy metals as (Mn, Ni, Cr, Zn, Cu, Co, Pb, Cd, As and Fe). Indirect geochemical background (IGB) of heavy metal was calculated by the iterative 2 standard deviations (SD) method.
The results of enrichment factor for heavy metals of the soil and sediment show that the all heavy metals in the studied samples were within Ef<2 indicate to depletion to minimal enrichment (i.e. no or minimal pollution). While Cd in the sample (5), Co in the sample (7), Cr in the sample (8) and Mn in the sample (1S) are within 2 ≤ EF < 5 indicate to Moderate enrichment. Contamination factor (Cf) for heavy metals of soil and sediment show that the all heavy metals in the studied samples were within Cf < 1 -Low contamination. While Sample "2" (Cd, Fe), sample "3" (Ni, Cr, Pb, and Cd), sample "4" (Mn, Fe) and sample "8" (Cr) are within 1 ≤ Cf < 3 moderate contamination.
Pollution load index result of all the soil and sediment samples are less than one indicate that "no pollution" are present, except sample 3 where the PLI value higher than 1 indicates the samples have been "polluted ". The modified degree of contamination (mCd) data indicate nil to a low degree of contamination for all of the soil and sediments samples.

Thirty-two soil samples were collected from the study area in October 2020 for geochemical and pollutants investigation of Shwan Sub-basin soil. All soil samples were analysed for different geochemical analyses. The analysis results revealed that the pH values in soil samples ranged from 7.12 to 7.56 with a mean of 7.327. According to the pH values detected in the soil samples, the soil is classified as neutral soil. The electrical conductivity ranged from 0.92 mmhos/cm to 7.8 mmhos/cm with a mean of 1.53 mmhos/cm. Thus, according to the detected electrical conductivity values, the soil was classified as non-saline to slightly saline. The organic matter ranged from 1.14% to 1.45% with a mean value of 1.326 %, while total organic carbon ranged from 0.66 % to 0.84 % with a mean value of 0.769 % which indicated the soil was characterized by low organic content. The results of the geochemical analysis revealed that the major and minor element mean concentrations were in the order Si> Ca> Al> Fe> Mg > K> Ti> Na> P> Mn> S> Cl> N. The average concentrations of trace elements in soil samples followed the decreasing order Sr > Cr> Ba> Zr> Ni> V> Zn> Ta> Rb> Cu> Nb> Y> Pb> Co> Ga> Mo> As> Th> Br> Sn> I. Furthermore, the comparison between heavy metal concentrations in the soil of the study area and metal concentrations in the world soil limit and Indirect Geochemical Background revealed an increase in metal concentrations of Cr, Ni, Zn, Co, As, Mo and Ta. Multivariate statistical analyses, such as Principal Component Analysis and Agglomerative Hierarchal Cluster Analysis, identified the potential sources of pollutants in the soil. Most metals are from natural sources and some of them are from anthropogenic sources mostly from agricultural activities mainly fertilizers use and the waste of animals breeding on farms. Besides industrial activities such as deposits of pollutants from emissions of petroleum refineries located inside or close to the study area. In addition, building blocks and paint factories.