TEMPO-oxidized cellulose nanofibers as interfacial strengthener in continuous-fiber reinforced polymer composites
In: Materials and design, Band 133, S. 340-348
ISSN: 1873-4197
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In: Materials and design, Band 133, S. 340-348
ISSN: 1873-4197
Asymmetric two-dimensional (2D) structures (often named Janus), like SeMoS and their nanotubes, have tremendous scope in material chemistry, nanophotonics, and nanoelectronics due to a lack of inversion symmetry and time-reversal symmetry. The synthesis of these structures is fundamentally difficult owing to the entropy-driven randomized distribution of chalcogens. Indeed, no Janus nanotubes were experimentally prepared, so far. Serendipitously, a family of asymmetric misfit layer superstructures (tubes and flakes), including LaX-TaX2 (where X = S/Se), were synthesized by high-temperature chemical vapor transport reaction in which the Se binds exclusively to the Ta atoms and La binds to S atoms rather than the anticipated random distribution.With increasing Se concentration, the LaS-TaX2 misfit structure gradually transformed into a new LaS-TaSe2-TaSe2 superstructure. No misfit structures were found for xSe = 1. These counterintuitive results shed light on the chemical selectivity and stability of misfit compounds and 2D alloys, in general. The lack of inversion symmetry in these asymmetric compounds induces very large local electrical dipoles. The loss of inversion and time-reversal symmetries in the chiral nanotubes offers intriguing physical observations and applications. © 2021 National Academy of Sciences. All rights reserved. ; ACKNOWLEDGMENTS. We thank Dr. Iddo Pinkas for the help with the Raman measurements. The support of the Israel Science Foundation (Grant 7130970101), Irving and Cherna Moskowitz Center for Nano and Bio-Nano Imaging, the Perlman Family Foundation, and the Kimmel Center for Nanoscale Science (Grant 43535000350000) are greatly acknowledged. Part of the TEM studies were conducted at the Laboratorio de Microscopias Avanzadas, Universidad de Zaragoza, Spain. S.H. and R.A. acknowledge funding by German Research Foundation (Deutsche Forschungsgemeinschaft project He 7675/1-1), by the Spanish Ministerio de Ciencia e Innovacion (PID2019-104739GB-100/AEI/ 10.13039/501100011033), and Government ...
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We present the analysis of a family of nanotubes (NTs) based on the quaternary misfit layered compound (MLC) YxLa1-xS-TaS2. The NTs were successfully synthesized within the whole range of possible compositions via the chemical vapor transport technique. In-depth analysis of the NTs using electron microscopy and spectroscopy proves the in-phase (partial) substitution of La by Y in the (La,Y)S subsystem and reveals structural changes compared to the previously reported LaS-TaS2 MLC-NTs. The observed structure can be linked to the slightly different lattice parameters of LaS and YS. Raman spectroscopy and infrared transmission measurements reveal the tunability of the plasmonic and vibrational properties. Density-functional theory calculations showed that the YxLa1-xS-TaS2 MLCs are stable in all compositions. Moreover, the calculations indicated that substitution of La by Sc atoms is electronically not favorable, which explains our failed attempt to synthesize these MLC and NTs thereof. © 2020 American Chemical Society. ; Israel Science Foundation, ISF: 7130970101 ; Center for Nanoscale Science and Technology, CNST: 43535000350000 ; 823717 ; Deutsche Forschungsgemeinschaft, DFG: HE 7675/1-1 ; University of the East, UE ; Ministerio de EconomÃa y Competitividad, MINECO: MAT2016-79776-P ; A.E. acknowledges the support by Act 211 Government of the Russian Federation, Contract No. 02.A03.21.0006. The support of the Israel Science Foundation (Grant No. 7130970101), Irving and Cherna Moskowitz Center for Nano and Bio-Nano Imaging, and the Perlman Family Foundation and the Kimmel Center for Nanoscale Science (Grant No. 43535000350000) is greatly acknowledged. The HRSTEM and EELS studies as well as some of the ED and TEM investigations were conducted at the Laboratorio de Microscopias Avanzadas, Instituto de Nanociencia de Aragon, Universidad de Zaragoza, Spain. We thank G. Antorrena and L. Casado (LMA-INA) for their help with the XRD acquisition and the electrical measurements, respectively. R.A. gratefully acknowledges the support from the Spanish Ministry of Economy and Competitiveness (MINECO) through Project Grant MAT2016-79776-P (AEI/FEDER, UE) and from the European Union H2020 program "ESTEEM3" (823717). S.H. acknowledges funding by the German Research Foundation (HE 7675/1-1). I.P. is the incumbent of the Sharon Zuckerman Research Fellow Chair.
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