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We determine the magnetic ground state of the FePc molecule on Au-supported thin films based on the observed values of orbital anisotropy and spectroscopic x-ray magnetic circular dichroism (XMCD) measurements at the Fe K and L edges. Starting from ab initio molecular orbital multiplet calculations for the isolated molecule, we diagonalize the spin-orbit interaction in the subspace spanned by the three lowest spin triplet states of 3A2g and 3Eg symmetry in the presence of a saturating magnetic field at a polar angle θ with respect to the normal to the plane of the film, plus an external perturbation representing the effect of the molecules in the stack on the FePc molecule under consideration. We find that the orbital moment of the ground state strongly depends on the magnetic field direction in agreement with the sum rule analysis of the L23-edge XMCD data. We calculate integrals over the XMCD spectra at the Fe K and L23 edges as used in the sum rules and explicitly show that they agree with the expectation values of the orbital moment and effective spin moment of the ground state. On the basis of this analysis, we can rule out alternative candidates proposed in the literature. ; J.B. and F.B. acknowledge the financial support of the Spanish MINEICO MAT2017-83468-R project, Aragonese E-12 17R RASMIA (co-funded by Fondo Social Europeo), and of the European Union FEDER (ES). We acknowledge support by the European Union COST MP1306 EUSPEC project. ; Peer reviewed

We investigate the ground state and low-energy spin-orbital excitations of a single iron(II) phthalocyanine molecule in isolation and on an oxidized Cu(110) surface. Considering the subspace spanned by the three lowest spin-triplet states of 3A2g and 3Eg symmetry, we diagonalize the Hamiltonian made of the anisotropic spin-orbit interaction and the ligand field splitting Δ, defined as the energy difference between 3Eg and 3A2g. We find that the ground state switches from a 3Eg-like state with large orbital moment and out-of-plane easy axis for Δ−60 meV. The analysis of the first excited states in the two regimes explains the zero-field splitting data reported for β-FePc as well as for FePc molecules adsorbed on an oxidized Cu(110) surface [N. Tsukahara et al., Phys. Rev. Lett. 102, 167203 (2009)]. Importantly, the calculated magnetic susceptibility obtained with the ab initio value Δ=93 meV compares remarkably well with the experimental data of β-FePc in the whole available temperature range of 1–300 K. ; This work has been partially supported by the Spanish MAT2017-83468-R project, Aragonese E-12 17R RASMIA (co-funded by Fondo Social Europeo), and of the European Union FEDER (ES). We also acknowledge funding by the European Union COST MP1306 EUSPEC project and by the Japan Society for the Promotion of Science (JSPS), Grant KAKENHI JP 16K05393. ; Peer reviewed

In this contribution we report on the structural and magnetic properties of an Fe phthalocyanine (FePc) thin film deposited on a silicon substrate. The planar FePc molecules order spontaneously in a standing configuration, i.e., with the molecular plane perpendicular to the substrate. The x-ray linear polarized absorption and x-ray magnetic circular dichroism experiments at the Fe-L2,3 edges at T = 6 K were performed, concluding that at this temperature the film displays magnetic anisotropy with the main easy axis perpendicular to the substrate. This result is explained in terms of the FePc single molecule anisotropy which has its larger moment in the molecule plane. Thus, the standing configuration in polycrystalline thin films favors statistically that, at the macroscopic array level, the magnetic easy anisotropy axis is normal to the substrate. ; The financial support of the Spanish MINECO MAT2014-53921-R and Aragonese DGA-IMANA E34, both cofunded by Fondo Social Europeo and European Union FEDER funds is acknowledged. T.G. acknowledges support from the National Science Foundation (NSF) DMR0847552 and the W.M. Keck Foundation. The XMCD experiments were performed at the ID08 (now ID32) beamline of the ESRF, experiment HE2486. This is a highly collaborative research. The experiments were conceived jointly, the data was extensively debated and the paper was written by multiple iteration between all the coauthors. Samples were fabricated, characterized and prepared at UCSD (T.G. and I.K.S.). The research at UCSD was supported by the Office of Basic Energy Science, U.S. Department of Energy, BES-DMS funded by the Department of Energy's Office of Basic Energy Science, DMR under Grant No. DE FG02 87ER-45332. ; Peer reviewed

7 páginas, 5 figuras, 1 tabla.-- PACS number(s): 75.30.Sg, 77.80.B-, 71.20.Eh ; A universal curve for the change in the magnetic entropy has been recently proposed for materials with second-order phase transitions. In this work we have studied the universal behavior of the magnetocaloric effect in the family of cobalt Laves phases, RCo2, and mixed manganites, La2/3(CaxSr(1−x))1/3MnO3, which exhibit first- and second-order phase transitions. The rescaled magnetic entropy change curves for different applied fields collapse onto a single curve for materials with second-order phase transition as opposed to the first-order phase transition compounds, for which this collapse does not hold. This result suggests that the universal curve may be used as a further criterion to distinguish the order of the phase transition. ; The financial support of MAT08-01077, DECRYPT, and CAMRADS is acknowledged. C. M. Bonilla acknowledge a Banco Santander grant and a Spanish MICINN grant. V. Franco acknowledges the Spanish MICINN and EU FEDER (Project No. MAT 2007-65227), and the PAI of Regional Government of Andalucía (Project No. P06-FQM- 01823). ; Peer reviewed

3 páginas, 3 figuras.-- Trabajo presentado al 11th Joint MMM-Intermag Conference celebrado en Washington (EE.UU) en 2010. ; A universal curve for the magnetic entropy change has been found to exist for a variety of materials with second order phase transitions. We have studied whether this universal behavior of the magnetocaloric effect is maintained in materials with first order phase transition, including RCo2 Laves phases and mixed La2/3(CaxSr1−x)1/3MnO3 manganites, which present both second order and first order magnetic ordering phase transitions. The rescaled magnetic entropy change curves for different applied fields collapse onto a single curve only for materials with second order phase transition. This universal curve may be used as a criterion for determining the order of magnetic phase transitions from purely magnetic measurements. ; The financial support of MAT08/1077, DECRYPT and CAMRADS is acknowledged. C.M. Bonilla acknowledges a Banco Santander grant and a Ministerio de Ciencia e Innovación grant. Victorino Franco acknowledges the Spanish Ministry of Science and Innovation and EU FEDER (Project No. MAT 2007-65227), and the PAI of the Regional Government of Andalucía (Project No. P06-FQM- 01823). ; Peer reviewed

Under the terms of the Creative Commons Attribution license.-- et al. ; The observation of an anomalous quadrupolar signal in x-ray magnetic circular dichroism (XMCD) at the Fe K-edge of iron phthalocyanine (FePc) films is reported. All ground states previously suggested for FePc are incompatible with the experimental data. Based on ab initio molecular orbital multiplet calculations of the isolated FePc molecule, we propose a model for the magnetic ground state of the FePc film that explains the XMCD data and reproduces the observed values of the orbital moments in the perpendicular and planar directions. ; The financial support of the Spanish financial agency MINECO MAT2011-23791 and MAT2014-53921-R, Aragonese DGA-IMANA E34 (co-funded by Fondo Social Europeo), and European Union FEDER funds is acknowledged. The research at UCSD was supported by the Office of Basic Energy Science, US Department of Energy, BES-DMS, funded by the Department of Energy Office of Basic Energy Science, DMR, under Grant No. DE FG03 87ER-45332. ; Peer Reviewed

Under the terms of the Creative Commons Attribution License 3.0 (CC-BY). ; The intramolecular exchange interactions within the single-molecule magnet (SMM) "butterfly" molecule [Fe3Ln(μ3-O) 2(CCl3COO)8(H2O)(THF)3], where Ln(III) represents a lanthanide cation, are determined in a combined experimental [x-ray magnetic circular dichroism (XMCD) and vibrating sample magnetometer (VSM)] and theoretical work. Compounds with Ln=Gd and Dy, which represent extreme cases where the rare earth presents single-ion isotropic and uniaxial anisotropy, on one hand, and with Ln=Lu and Y(III) as pseudolanthanide substitutions that supply a nonmagnetic Ln reference case, on the other hand, are studied. The Dy single-ion uniaxial anisotropy is estimated from ab initio calculations. Low-temperature (T 2.5 K) hard x-ray XMCD at the Ln L 2,3 edges and VSM measurements as a function of the field indicate that the Ln moment dominates the polarization of the molecule by the applied field. Within the {Fe3LnO2} cluster the Ln-Fe3 subcluster interaction is determined to be antiferromagnetic in both Dy and Gd compounds, with values J Dy-Fe3=-0.4 K and J Gd-Fe3=-0.25 K, by fitting to spin Hamiltonian simulations that consider the competing effects of intracluster interactions and the external applied magnetic field. In the uniaxial anisotropic {Fe3DyO2} case, a field-induced reorientation of the Fe3 and Dy spins from an antiparallel to a parallel orientation takes place at a threshold field (μ0H=4 T). In contrast, in isotropic {Fe3GdO2} this reorientation does not occur. © 2013 American Physical Society. ; The financial support of Spanish MINECO Grant No. MAT2011-23791, the Alexander Von Humboldt Foundation (D.P.), and Aragonese DGA-IMANA E34 (cofunded by Fondo Social Europeo) and that received from European Union FEDER funds are also acknowledged. L.B.R. acknowledges the Spanish MINECO FPU 2010 grant. ; Peer Reviewed

7 páginas, 7 figuras.-- PACS number(s): 75.70.Rf, 75.70.Ak, 75.50.Bb.-- et al. ; We study the enhanced magnetic moment observed in epitaxial magnetite (Fe3O4) ultrathin films (t<15 nm) grown on MgO (001) substrates by means of pulsed laser deposition. The Fe3O4 (001) thin films exhibit high crystallinity, low roughness, and sharp interfaces with the substrate, and the existence of the Verwey transition at thicknesses down to 4 nm. The evolution of the Verwey transition temperature with film thickness shows a dependence with the antiphase boundaries density. Superconducting quantum interference device (SQUID) and vibrating sample magnetometry measurements in ultrathin films show a magnetic moment much higher than the bulk magnetite value. In order to study the origin of this anomalous magnetic moment, polarized neutron reflectivity (PNR), and x-ray magnetic circular dichroism (XMCD) experiments have been performed, indicating a decrease in the magnetization with decreasing sample thickness. X-ray photoemission spectroscopy measurements show no metallic Fe clusters present in the magnetite thin films. Through inductively coupled plasma mass spectroscopy and SQUID magnetometry measurements performed in commercial MgO (001) substrates, the presence of Fe impurities embedded within the substrates has been observed. Once the substrate contribution has been corrected, a decrease in the magnetic moment of magnetite thin films with decreasing thickness is found, in good agreement with the PNR and XMCD measurements. Our experiments suggest that the origin of the enhanced magnetic moment is not intrinsic to magnetite but due to the presence of Fe impurities in the MgO substrates. ; This work has been financially supported by Spanish Ministry of Science through Projects No. MAT2008-06567-C02 and No. MAT2008-01077, and the Regional Government of Aragón (E-26, E-69, and E-34). ; Peer reviewed

Scanning tunneling microscopy and x-ray absorption spectroscopic results at the Fe K edge of Fe phthalocyanine (FePc) thin films grown on Au substrates, together with theoretical calculations, allow us to refine the structure of the film. In particular, we show that the columnar stacking of the FePc molecules is different from that found in bulk ¿ and ß phases. Moreover, the molecules do not lay parallel to the surface of the substrate. These structural findings are relevant to understand magnetism of FePc films. ; The financial support of the Spanish financial agency MINECO MAT2011-2379 and MAT2014-53921-R, Aragonese DGA-IMANA E34 (co-funded by European Social Fund), as well as European Union FEDER funds is acknowledged. The sample preparation and initial structural characterization were supported by the Office of Basic Energy Science, U.S. Department of Energy, BES-DMS funded by the Department of Energy's Office of Basic Energy Science, DMR under Grant No. DE FG03 87ER-45332 and NSF DMR 0847552. ; Peer Reviewed

Recently, mixed honeycomb–kagome lattices featuring metal–organic networks have been theoretically proposed as topological insulator materials capable of hosting nontrivial edge states. This new family of so-called "organic topological insulators" are purely two-dimensional and combine polyaromatic-flat molecules with metal adatoms. However, their experimental validation is still pending given the generalized absence of edge states. Here, we generate one such proposed network on a Cu(111) substrate and study its morphology and electronic structure with the purpose of confirming its topological properties. The structural techniques reveal a practically flawless network that results in a kagome network multi-band observed by angle-resolved photoemission spectroscopy and scanning tunneling spectroscopy. However, at the network island borders we notice the absence of edge states. Bond-resolved imaging of the network exhibits an unexpected structural symmetry alteration that explains such disappearance. This collective lifting of the network symmetry could be more general than initially expected and provide a simple explanation for the recurrent experimental absence of edge states in predicted organic topological insulators. ; We gratefully acknowledge financial support from the Spanish Ministry of Economy, Industry and Competitiveness (MINECO, Grant No. MAT2016-78293-C6-6-R, MAT2016-78293-C6-4-R and MAT2017-83468-R) and the Ministry of Science and Innovation (MICINN, Grant No. PID2019-107338RB-C6-3 and PID2019-107338RB-C6-4), from the regional Government of Aragon (E12-20R RASMIA project and Formación de Personal Investigador, 2018 grant) and the regional Government of the Basque Country (IT-1255-19), from the "Juan de la Cierva" program, and from the European Regional Development Fund (ERDF) under the program Interreg V-A España-Francia-Andorra (Contract No. EFA194/16 TNSI). C. D. is supported by the Royal Society University Research Fellowship (URF/R1/201158). ; We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI). ; Peer reviewed

Under the terms of the Creative Commons Attribution License 3.0 (CC-BY).-- et al. ; The crossover from antidot to dot magnetic behavior on arrays patterned in a ferromagnetic thin film has been achieved by modifying only the geometry. A series of antidot arrays has been fabricated on cobalt with fixed diameter d and by reducing the period of the array p from pd to p

The study of ratchet and crossed-ratchet effects in magnetic domain wall motion through 2D arrays of asymmetric holes is extended in this article to the submicrometric limit in hole size (small size regime). Therefore, the gap has been closed between the 2D ratchets in the range of tens-of-micrometers (large size regime) and the small size regime 1D ratchets based on nanowires. The combination of Kerr microscopy, X-ray PhotoEmission Electron Microscopy and micromagnetic simulations has allowed a full magnetic characterisation of both the domain wall (DW) propagation process over the whole array and the local DW morphology and pinning at the holes. It is found that the 2D small size limit is driven by the interplay between DW elasticity and half vortex propagation along hole edges: as hole size becomes comparable to DW width, flat DW propagation modes are favoured over kinked DW propagation due to an enhancement of DW stiffness, and pinned DW segments adopt asymmetric configurations related with Néel DW chirality. Nevertheless, both ratchet and crossed-ratchet effects have been experimentally found, and we propose a new ratchet/inverted-ratchet effect in the submicrometric range driven by magnetic fields and electrical currents respectively. ; The financial support of the Spanish MINECO MAT2014-53921-R, FIS2013-45469 and FIS2016-76058 (AEI) and the Aragonese DGA IMANAE34 and CAMRADSE69, all of them cofunded by Fondo Social Europeo and European Union FEDER funds, is acknowledged. A. H-R acknowledges the support from FCT of Portugal (Grant SFRH/BPD/90471/2012). ; Peer Reviewed