Analysis of the distributions of hourly NO2 concentrations contributing to annual average NO2 concentrations across the European monitoring network between 2000 and 2014
Exposure to nitrogen dioxide (NO 2 ) is associated with negative human health effects, both for short-term "peak" concentrations and from long-term exposure to a wider range of NO 2 concentrations. For the latter, the European Union has established an air quality limit value of 40 µ g m −3 as an annual average. However, factors such as proximity and strength of local emissions, atmospheric chemistry, and meteorological conditions mean that there is substantial variation in the hourly NO 2 concentrations contributing to an annual average concentration. The aim of this analysis was to quantify the nature of this variation at thousands of monitoring sites across Europe through the calculation of a standard set of "chemical climatology" statistics. Specifically, at each monitoring site that satisfied data capture criteria for inclusion in this analysis, annual NO 2 concentrations, as well as the percentage contribution from each month, hour of the day, and hourly NO 2 concentrations divided into 5 µ g m −3 bins were calculated. Across Europe, 2010–2014 average annual NO 2 concentrations (NO 2AA ) exceeded the annual NO 2 limit value at 8 % of > 2500 monitoring sites. The application of this "chemical climatology" approach showed that sites with distinct monthly, hour of day, and hourly NO 2 concentration bin contributions to NO 2AA were not grouped into specific regions of Europe, furthermore, within relatively small geographic regions there were sites with similar NO 2AA , but with differences in these contributions. Specifically, at sites with highest NO 2AA , there were generally similar contributions from across the year, but there were also differences in the contribution of peak vs. moderate hourly NO 2 concentrations to NO 2AA , and from different hours across the day. Trends between 2000 and 2014 for 259 sites indicate that, in general, the contribution to NO 2AA from winter months has increased, as has the contribution from the rush-hour periods of the day, while the contribution from peak hourly NO 2 concentrations has decreased. The variety of monthly, hour of day and hourly NO 2 concentration bin contributions to NO 2AA , across cities, countries and regions of Europe indicate that within relatively small geographic areas different interactions between emissions, atmospheric chemistry and meteorology produce variation in NO 2AA and the conditions that produce it. Therefore, measures implemented to reduce NO 2AA in one location may not be as effective in others. The development of strategies to reduce NO 2AA for an area should therefore consider (i) the variation in monthly, hour of day, and hourly NO 2 concentration bin contributions to NO 2AA within that area; and (ii) how specific mitigation actions will affect variability in hourly NO 2 concentrations.