Suchergebnisse

Electro-hydrodynamic processing, comprising electrospraying and electrospinning techniques, has emerged as a versatile technology to produce nanostructured fiber-based and particle-based materials. In this work, an antimicrobial active multilayer system comprising a commercial polyhydroxyalkanoate substrate (PHA) and an electrospun PHA coating containing in situ-stabilized silver nanoparticles (AgNPs) was successfully developed and characterized in terms of morphology, thermal, mechanical, and barrier properties. The obtained materials reduced the bacterial population of Salmonella enterica below the detection limits at very low silver loading of 0.002 ± 0.0005 wt %. As a result, this study provides an innovative route to generate fully renewable and biodegradable materials that could prevent microbial outbreaks in food packages and food contact surfaces. ; This work was financially supported by the Spanish Ministry of Economy and Competitiveness (AGL2015-63855-C2-1-R). Jinneth Lorena Castro-Mayorga is supported by the Administrative Department of Science, Technology and Innovation (Colciencias) of the Colombian Government. Maria Jose Fabra is recipient of a Ramon y Cajal contract from the Spanish Ministry of Economy and Competitiveness. Maria Reis from Universidade Nova de Lisboa, Lisbon, Portugal is acknowledged for supplying the PHBV18 material.

Electro-hydrodynamic processing, comprising electrospraying and electrospinning techniques, has emerged as a versatile technology to produce nanostructured fiber-based and particle-based materials. In this work, an antimicrobial active multilayer system comprising a commercial polyhydroxyalkanoate substrate (PHA) and an electrospun PHA coating containing in situ-stabilized silver nanoparticles (AgNPs) was successfully developed and characterized in terms of morphology, thermal, mechanical, and barrier properties. The obtained materials reduced the bacterial population of Salmonella enterica below the detection limits at very low silver loading of 0.002 ± 0.0005 wt %. As a result, this study provides an innovative route to generate fully renewable and biodegradable materials that could prevent microbial outbreaks in food packages and food contact surfaces. ; This work was financially supported by the Spanish Ministry of Economy and Competitiveness (AGL2015-63855-C2-1-R). Jinneth Lorena Castro-Mayorga is supported by the Administrative Department of Science, Technology and Innovation (Colciencias) of the Colombian Government. Maria Jose Fabra is recipient of a Ramon y Cajal contract from the Spanish Ministry of Economy and Competitiveness. Maria Reis from Universidade Nova de Lisboa, Lisbon, Portugal is acknowledged for supplying the PHBV18 material. We acknowledge support by the CSIC Open Access Publication Initiative through its Unit of Information Resources for Research (URICI).

Active biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) melt mixed nanocomposites and bilayer structures containing copper oxide (CuO) nanoparticles were developed and characterized. The bilayer structures consisted of a bottom layer of compression molded PHBV3 (3% mol valerate) coated with an active electrospun fibers mat made with CuO nanoparticles and PHBV18 (18% valerate) derived from microbial mixed cultures and cheese whey. The results showed that the water vapor permeability increased with the CuO addition while the oxygen barrier properties were slightly enhanced by the addition of 0.05 wt % CuO nanoparticles to nanocomposite films but a negligible effect was registered for the bilayer structures. However, the mechanical properties were modified by the addition of CuO nanoparticles. Interestingly, by incorporating highly dispersed and distributed CuO nanoparticles in a coating by electrospinning, a lower metal oxide loading was required to exhibit significant bactericidal and virucidal performance against the food-borne pathogens Salmonella enterica, Listeria monocytogenes, and murine norovirus. The biodisintegration tests of the samples under composting conditions showed that even the 0.05% CuO-coated structures biodegraded within 35 days. ; This work was financially supported by the Spanish Ministry of Economy and Competitiveness (project AGL2015–63855-C2–1-R). J.L.C.-M. is supported by the Administrative Department of Science, Technology and Innovation (Colciencias) of Colombian Government. M.J.F. is recipient of a Ramon y Cajal contract from the Spanish Ministry of Economy and Competitiveness. ; Peer reviewed