Suchergebnisse

Remaining silicon in SiC-based materials produced via reactive infiltration limits their use in high-temperature applications due to the poor mechanical properties of silicon: low fracture toughness, extreme fragility and creep phenomena above 1000 °C. In this paper SiC–FeSi2 composites are fabricated by reactive infiltration of Si–Fe alloys into porous Cf/C preforms. The resulting materials are SiC/FeSi2 composites, in which remaining silicon is reduced by formation of FeSi2. For the richest Fe alloys (35 wt% Fe) a nominal residual silicon content below 1% has been observed. However this, the relatively poor mechanical properties (bending strength) measured for those resulting materials can be explained by the thermal mismatch of FeSi2 and SiC, which weakens the interface and does even generate new porosity, associated with a debonding phenomenon between the two phases. ; Authors would like acknowledge the financial support received from the Generalitat Valenciana (PROMETEO II/2014/004-FEDER, PhD grant Vali+d and Santiago Grisolia program, GRISOLIA/2013/023), and the European Union's Seventh Framework Programme (FP7/2007-2013) under the HELM project, Grant agreement no. 280464 are gratefully acknowledged.