Suchergebnisse

We emphasize that the completeness of the partition function, that is, the use of a converged partition function at the typical temperature range of the survey, is very important to decrease the uncertainty on this quantity and thus to derive reliable interstellar molecular densities. In that context, we show how the use of different approximations for the rovibrational partition function together with some interpolation and/or extrapolation procedures may affect the estimate of the interstellar molecular column density. For that purpose, we apply the partition function calculations to astronomical observations performed with the IRAM-30m telescope towards the NGC 7538–IRS1 source of two N-bearing molecules: isocyanic acid (HNCO, a quasilinear molecule) and methyl cyanide (CH3CN, a symmetric top molecule). The case of methyl formate (HCOOCH3), which is an asymmetric top O-bearing molecule containing an internal rotor is also discussed. Our analysis shows that the use of different partition function approximations leads to relative differences in the resulting column densities in the range 9–43%. Thus, we expect this work to be relevant for surveys of sources with temperatures higher than 300K and to observations in the infrared. ; This work is partly supported by CMST COST Action CM1401 Our Astro-Chemical History and CMST COST Action CM1405 MOLIM. The work of C.F. is supported by the French National Research Agency in the framework of the Investissements d'Avenir program (ANR-15- IDEX-02), through the funding of the "Origin of Life" project of the Université Grenoble-Alpes. C.C. and C.F. acknowledge funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme, for the Project "The Dawn of Organic Chemistry" (DOC), grant agreement No 741002. I.K. would like to thank the French programme of Chimie Interstellaire PCMI. C.F. and D.F. acknowledge support from the Italian Ministry of Education, Universities and Research, project SIR (RBSI14ZRHR). E.A.B. acknowledges support from NSF (AST-1514670) and NASA (NNX16AB48G). M.C. acknowledges the financial support from FIS2014-53448-C2-2-P (MINECO, Spain), from the Centro de Estudios Avanzados de Física, Matemáticas y Computación (CEAFMC) of the University of Huelva and from the Consejería de Conocimiento, Investigación y Universidad, Junta de Andalucía and European Regional Development Fund (ERDF), ref. SOMM17/6105/UGR.

We report the discovery of doubly deuterated water (D2O, heavy water) in the interstellar medium. Using the James Clerk Maxwell Telescope and the Caltech Submillimeter Observatory 10 m telescope, we detected the 1_10–1_01 transition of para-D2O at 316.7998 GHz in both absorption and emission toward the protostellar binary system IRAS 16293-2422. Assuming that the D2O exists primarily in the warm regions where water ices have been evaporated (i.e., in a "hot corino" environment), we determine a total column density of N(D2O) of 1.0x10^13 cm^-2 and a fractional abundance of D2O/H2 = 1.7x10^-10. The derived column density ratios for IRAS 16293-2422 are D2O/HDO = 1.7x10^-3 and D2O/H2O = 5x10^-5 for the hot corino gas. Steady state models of water ice formation, either in the gas phase or on grains, predict D2O/HDO ratios that are about 4 times larger than that derived from our observations. For water formation on grain surfaces to be a viable explanation, a larger H2O abundance than that measured in IRAS 16293-2422 is required. Alternatively, the observed D2O/HDO ratio could be indicative of gas-phase water chemistry prior to a chemical steady state being attained, such as would have occurred during the formation of this source. Future observations with the Herschel Space Observatory satellite will be important for settling this issue. ; The CSO is funded by the NSF through grant AST 22-09008. This work was supported by the NASA Goddard Center for Astrobiology and, through Cooperative Agreement NCC2-1412, by NASA's Long Term Space Astrophysics Program. J. R. Pardo and J. Cernicharo thank the Spanish MEC for funding support under grant AYA2003-02785 and the Madrid Community Government under grant S-0505 ESP-0237 (ASTROCAM). ; Peer reviewed

Aims. The Seeds Of Life In Space IRAM/NOEMA large program aims at studying a set of crucial complex organic molecules in a sample of sources with a well-known physical structure that covers the various phases of solar-type star formation. One representative object of the transition from the prestellar core to the protostar phases has been observed toward the very low luminosity object (VeLLO) L1521F. This type of source is important to study to link prestellar cores and Class 0 sources and also to constrain the chemical evolution during the process of star formation. Methods. Two frequency windows (81.6-82.6 GHz and 96.65-97.65 GHz) were used to observe the emission from several complex organics toward the L1521F VeLLO. These setups cover transitions of ketene (H2CCO), propyne (CH3CCH), formamide (NH2CHO), methoxy (CH3O), methanol (CH3OH), dimethyl ether (CH3OCH3), and methyl formate (HCOOCH3). Results. Only two transitions of methanol (A+, E2) have been detected in the narrow window centered at 96.7 GHz (with an upper limit on E1) in a very compact emission blob (∼7″ corresponding to ∼1000 au) toward the northeast of the L1521F protostar. The CS 2-1 transition is also detected within theWideX bandwidth. Consistently with what has been found in prestellar cores, the methanol emission appears ∼1000 au away from the dust peak. The location of the methanol blob coincides with one of the filaments that have previously been reported in the literature. The excitation temperature of the gas inferred from methanol is (10 ± 2) K, while the H2 gas density (estimated from the detected CS 2-1 emission and previous CS 5-4 ALMA observations) is a factor >25 higher than the density in the surrounding environment (n(H2) ≥ 107 cm-3). Conclusions. Based on its compactness, low excitation temperature, and high gas density, we suggest that the methanol emission detected with NOEMA is (i) either a cold and dense shock-induced blob that formed recently (≤ a few hundred years) by infalling gas or (ii) a cold and dense fragment that may just have been formed as a result of the intense gas dynamics within the L1521F VeLLO system. © 2020 C. Favre et al. ; Russian Science Foundation, RSF: 18–12–00351 ; Australian Education International, Australian Government, AEI: MDM-2017-0737 ; Agence Nationale de la Recherche, ANR: ANR-15-IDEX-02 ; European Research Council, ERC ; Horizon 2020 Framework Programme, H2020: 741002 ; Ministerio de Economía y Competitividad, MINECO: AYA2016-79006-P ; European Regional Development Fund, FEDER: ESP2017-86582-C4-1-R ; Acknowledgements. We thank our referee, Dr. Kazuki Tokuda, (i) for his fruitful comments that have improved the quality of our paper and (ii) for sharing his continuum emission map. This work is supported by the French National Research Agency in the framework of the Investissements d'Avenir program (ANR-15-IDEX-02), through the funding of the "Origin of Life" project of the Univ. Grenoble-Alpes. C.F., C.V. and C.C. acknowledge the funding from the European Research Council (ERC) under the European Unions Horizon 2020 research and innovation programme, for the Project The Dawn of Organic Chemistry (DOC), grant agreement No 741002. I.J.-S. has received partial support from the Spanish FEDER (project number ESP2017-86582-C4-1-R), and State Research Agency (AEI) through project number MDM-2017-0737 Unidad de Excelencia María de Maeztu–Centro de Astrobiología (INTA-CSIC). A.P. acknowledges the financial support of the Russian Science Foundation project 18–12–00351. A.C.-T acknowledges support from MINECO project AYA2016-79006-P.

Aims. The Seeds Of Life In Space IRAM/NOEMA large program aims at studying a set of crucial complex organic molecules in a sample of sources with a well-known physical structure that covers the various phases of solar-type star formation. One representative object of the transition from the prestellar core to the protostar phases has been observed toward the very low luminosity object (VeLLO) L1521F. This type of source is important to study to link prestellar cores and Class 0 sources and also to constrain the chemical evolution during the process of star formation. Methods. Two frequency windows (81.6-82.6 GHz and 96.65-97.65 GHz) were used to observe the emission from several complex organics toward the L1521F VeLLO. These setups cover transitions of ketene (HCCO), propyne (CHCCH), formamide (NHCHO), methoxy (CHO), methanol (CHOH), dimethyl ether (CHOCH), and methyl formate (HCOOCH). Results. Only two transitions of methanol (A, E) have been detected in the narrow window centered at 96.7 GHz (with an upper limit on E) in a very compact emission blob (∼7″ corresponding to ∼1000 au) toward the northeast of the L1521F protostar. The CS 2-1 transition is also detected within theWideX bandwidth. Consistently with what has been found in prestellar cores, the methanol emission appears ∼1000 au away from the dust peak. The location of the methanol blob coincides with one of the filaments that have previously been reported in the literature. The excitation temperature of the gas inferred from methanol is (10 ± 2) K, while the H gas density (estimated from the detected CS 2-1 emission and previous CS 5-4 ALMA observations) is a factor >25 higher than the density in the surrounding environment (n(H) ≥ 10 cm). Conclusions. Based on its compactness, low excitation temperature, and high gas density, we suggest that the methanol emission detected with NOEMA is (i) either a cold and dense shock-induced blob that formed recently (≤ a few hundred years) by infalling gas or (ii) a cold and dense fragment that may just have been formed as a result of the intense gas dynamics within the L1521F VeLLO system. ; With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)

Context. Low-mass protostars drive powerful molecular outflows that can be observed with millimetre and submillimetre telescopes. Various sulfuretted species are known to be bright in shocks and could be used to infer the physical and chemical conditions throughout the observed outflows. Aims. The evolution of sulfur chemistry is studied along the outflows driven by the NGC 1333-IRAS4A protobinary system located in the Perseus cloud to constrain the physical and chemical processes at work in shocks. Methods. We observed various transitions from OCS, CS, SO, and SO2 towards NGC 1333-IRAS4A in the 1.3, 2, and 3 mm bands using the IRAM NOrthern Extended Millimeter Array and we interpreted the observations through the use of the Paris-Durham shock model. Results. The targeted species clearly show different spatial emission along the two outflows driven by IRAS4A. OCS is brighter on small and large scales along the south outflow driven by IRAS4A1, whereas SO2 is detected rather along the outflow driven by IRAS4A2 that is extended along the north east-south west direction. SO is detected at extremely high radial velocity up to + 25 km s-1 relative to the source velocity, clearly allowing us to distinguish the two outflows on small scales. Column density ratio maps estimated from a rotational diagram analysis allowed us to confirm a clear gradient of the OCS/SO2 column density ratio between the IRAS4A1 and IRAS4A2 outflows. Analysis assuming non Local Thermodynamic Equilibrium of four SO2 transitions towards several SiO emission peaks suggests that the observed gas should be associated with densities higher than 105 cm-3 and relatively warm (T > 100 K) temperatures in most cases. Conclusions. The observed chemical differentiation between the two outflows of the IRAS4A system could be explained by a different chemical history. The outflow driven by IRAS4A1 is likely younger and more enriched in species initially formed in interstellar ices, such as OCS, and recently sputtered into the shock gas. In contrast, the longer and likely older outflow triggered by IRAS4A2 is more enriched in species that have a gas phase origin, such as SO2. © ESO 2020. ; V.T. is grateful to Sylvie Cabrit and Guillaume Pineau des Forêts for stimulating discussions on the chemistry in shocks. The authors acknowledge the CALYPSO consortium for the use of the CALYPSO dataset. This work is based on observations carried out with the IRAM PdBI/NOEMA Interferometer under project numbers V05B and V010 (PI: M.V. Persson), U003 (PI: V. Taquet), and L15AA (PI: C. Ceccarelli and P. Caselli). IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain). V.T. acknowledges the financial support from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement n. 664931. This work was supported by (i) the PRIN-INAF 2016 "The Cradle of Life – GENESIS-SKA (General Conditions in Early Planetary Systems for the rise of life with SKA)", (ii) the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme, for the Project "The Dawn of Organic Chemistry" (DOC), grant agreement No 741002, and (iii) the European MARIE SKŁODOWSKA-CURIE ACTIONS under the European Union's Horizon 2020 research and innovation programme, for the Project "Astro-Chemistry Origins" (ACO), Grant No 811312. C.F. acknowledges support from the French National Research Agency in the framework of the Investissements d'Avenir program (ANR-15-IDEX-02), through the funding of the "Origin of Life" project of the Université Grenoble-Alpes.

The study of hot corinos in solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already during Class I phase, which therefore represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here, we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA (Atacama Large Millimeter/submillimeter Array) Large Program FAUST (Fifty AU STudy of the chemistry in the disc/envelope system of solar-like protostars).We detected several lines from methanol and its isotopologues (13CH3OH and CH2DOH), methyl formate, and ethanol. Lines are bright towards the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines' non-LTE analysis constrains the gas temperature (100 K), density (1.5 × 108 cm3), and emitting size (10 au in radius). All CH3OH and 13CH3OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on this work, little chemical evolution from Class 0 to I hot corinos occurs. ; With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)