Organometallic Compounds: Volume Two. The Transition Elements
In: Springer eBook Collection
to Volume Two -- Classification -- The 18-electron rule -- 1. Two-Electron Ligands -- A. Classification -- B. The preparation of olefin-transition metal complexes -- C. A molecular orbital description of the bonding in organo-metallic complexes -- D. A description of the bonding of 2-electron ligands to transition metals -- E. General comments of 2-electron ligands -- F. Particular complexes of metals with 2-electron ligands -- 2. Three-Electron Ligands -- A. Preparation of ?-enyl complexes -- B. The structure of ?-enyl complexes -- C. The ?-allyl metal bond -- D. Dynamic equilibria in allyl complexes -- E. The chemistry of particular ?-enyl complexes -- 3. Four-Electron Ligands -- A. Some differences between unconjugated and conjugated olefin ligands -- B. The bonding of 4-electron ligands to transition metals -- C. Particular studies -- 4. Five-Electron Ligands -- A. Cyclopentadienyl metal complexes -- B. ?-Cyclopentadienyl transition metal complexes -- C. Cyclopentadienide transition metal complexes -- D. The bonding in mono-?-cyclopentadienyl transition metal complexes -- E. ?-Cyclopentadienyl carbonyl complexes -- F. ?-Cyclopentadienyl nitrosyl complexes -- G. Brief notes on binuclear ?-cyclopentadienyl complexes containing bridging ligands -- H. ?-Cyclopentadienyl hydride complexes -- I. ?-Cyclopentadienyl halides and oxides -- J. Other 5-electron ligands -- K. The organic chemistry of ?-cyclopentadienyl transition metal complexes -- L. Some particular reactions -- 5. Six-Electron Ligands -- A. Arene transition metal complexes -- (a) Preparation -- B. Olefin 6-electron ligands -- C. Transition metal complexes containing ?-bonded heterocyclic ligands -- 6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes -- A. 7-Electron ligands -- B. Mixed sandwich complexes -- C. Metal complexes formed from azulenes -- D. Cyclo-octatetraene complexes -- 7. One-Electron Ligands -- I.1. Hydrocarbon alkyl and aryl complexes -- I.2 Transition metal-acyl complexes -- I.3. ?-Cyclopentadienyl complexes -- II. Transition metal fluorocarbon complexes -- III. Transition metal acetytides and alkynyls -- 8. Organometallic Complexes Formed From Acetylenes -- A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands -- B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands -- C. Monoacetylene trinuclear complexes -- D. Monoacetylene tetranuclear complexes -- E. Bis-acetylene mononuclear complexes -- F. Bis-acetylene trinuclear complexes -- G. Tris-acetylene mononuclear complexes -- H. Tris-acetylene binuclear complexes -- I. Miscellaneous -- 9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions -- A. Some chemistry of transition metal hydride complexes -- B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions -- C. Homogeneous hydrogenation of olefins and acetylenes -- D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes -- E. Hydroformylation and related carhonylation reactions -- F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts -- G. Miscellaneous -- Author -- Subject -- Crystal Structures>.