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Nanodomain structure of single crystalline nickel oxide
In this work we present a comprehensive study of the domain structure of a nickel oxide single crystal grown by floating zone melting and suggest a correlation between point defects and the observed domain structure. The properties and structure of domains dictate the dynamics of resistive switching, water splitting and gas sensing, to name but a few. Investigating the correlation between point defects and domain structure can provide a deeper understanding of their formation and structure, which potentially allows one to tailor domain structure and the dynamics of the aforementioned applications. A range of inhomogeneities are observed by diffraction and microscopy techniques. X-ray and low-energy electron diffraction reveal domains on the submicron- and nanometer-scales, respectively. In turn, these domains are visualised by atomic force and scanning tunneling microscopy (STM), respectively. A comprehensive transmission electron microscopy (TEM) study reveals inhomogeneities ranging from domains of varying size, misorientation of domains, variation of the lattice constant and bending of lattice planes. X-ray photoelectron spectroscopy and electron energy-loss spectroscopy indicate the crystal is Ni deficient. Density functional theory calculations-considering the spatial and electronic disturbance induced by the favourable nickel vacancy-reveal a nanoscale distortion comparable to STM and TEM observations. The different inhomogeneities are understood in terms of the structural relaxation induced by ordering of nickel vacancies, which is predicted to be favourable. ; Funding Agencies|Russian Science FoundationRussian Science Foundation (RSF) [18-12-00492]; RFBRRussian Foundation for Basic Research (RFBR) [19-29-03021]; Research Facility Center at the ISSP of RAS; Erasmus Plus mobility Grants [2016-1-IE02-KA107-000479, 2017-1-IE02-KA107-000538 2018-1-IE02-KA107-000589]; Ministry of Science and Higher Education of the Russian Federation [K2-2019-001, 211]; Swedish Research Council (VR)Swedish Research Council [2019-05600]; Swedish Government Strategic Research Areas in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009-00971]; Irish Research Council Laureate AwardIrish Research Council for Science, Engineering and Technology [IRCLA/2019/171]
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Fine roots stimulate nutrient release during early stages of leaf litter decomposition in a Central Amazon rainforest
This is the final version. Available on open access from Springer via the DOI in this record ; Purpose Large parts of the Amazon rainforest grow on weathered soils depleted in phosphorus and rock-derived cations. We tested the hypothesis that in this ecosystem, fine roots stimulate decomposition and nutrient release from leaf litter biochemically by releasing enzymes, and by exuding labile carbon stimulating microbial decomposers. Methods We monitored leaf litter decomposition in a Central Amazon tropical rainforest, where fine roots were either present or excluded, over 188 days and added labile carbon substrates (glucose and citric acid) in a fully factorial design. We tracked litter mass loss, remaining carbon, nitrogen, phosphorus and cation concentrations, extracellular enzyme activity and microbial carbon and nutrient concentrations. Results Fine root presence did not affect litter mass loss but significantly increased the loss of phosphorus and cations from leaf litter. In the presence of fine roots, acid phosphatase activity was 43.2% higher, while neither microbial stoichiometry, nor extracellular enzyme activities targeting carbon- and nitrogen-containing compounds changed. Glucose additions increased phosphorus loss from litter when fine roots were present, and enhanced phosphatase activity in root exclusions. Citric acid additions reduced litter mass loss, microbial biomass nitrogen and phosphorus, regardless of fine root presence or exclusion. Conclusions We conclude that plant roots release significant amounts of acid phosphatases into the litter layer and mobilize phosphorus without affecting litter mass loss. Our results further indicate that added labile carbon inputs (i.e. glucose) can stimulate acid phosphatase production by microbial decomposers, highlighting the potential importance of plant-microbial feedbacks in tropical forest ecosystems. ; Inter-American Development Bank ; Brazilian Ministry of Science, Technology, Innovation and Communications ; Brazil's Coordination for the Improvement of Higher Education Personnel (CAPES) ; Amazonas Research Foundation (FAPEAM) ; European Research Council (ERC) ; European Union Horizon 2020 ; Natural Environment Research Council (NERC) ; DFG ; FAPESP grant
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