Suchergebnisse

We acknowledge funding from Science Foundation Ireland via the AMBER research centre (SFI/12/RC/2278) and a PI award (11/PI/1087). We are grateful for financial support from the European research Council (SEMANTICS) and the European Union Seventh Framework Programme under grant agreements n?604391 and n?696656 Graphene Flagship.

PUBLISHED ; This work was primarily supported by an SFI PYRA grant as well as the SFI-funded AMBER research centre (SFI/12/RC/2278) as part of the platform projects program. In addition, we 20 acknowledge the European Union Seventh Framework Program under grant agreement n?604391 Graphene Flagship.

PUBLISHED ; Export Date: 15 September 2016 ; Here we demonstrate that liquid phase exfoliation can be used to convert layered crystals of nickel hydroxide into Ni(OH)2 nanosheets in relatively large quantities and without the need for ion intercalation. While other procedures require harsh synthesis conditions and multiple reaction steps, this method involves ultrasonication of commercially available powders in aqueous surfactant solutions and so is relatively mild and potentially scalable. Such mild exfoliation is possible because the surface energy of Ni(OH)2, as measured by inverse gas chromatography, is relatively low at ?70 mJ m?2, similar to other layered materials. TEM, AFM, XPS and Raman spectroscopy show the exfoliated nanosheets to be relatively thin (mean ?10 monolayers thick) and of good quality. Size selection by liquid cascade centrifugation allowed the production of samples with mean nanosheet lengths ranging from 55 to 195 nm. Optical measurements on dispersions showed the optical absorption coefficient spectra to be relatively invariant with nanosheet size while the scattering coefficient spectra varied strongly with size. The resultant size-dependence allows the extinction spectra to be used to estimate nanosheet size as well as concentration. We used the exfoliated nanosheets to prepare thin film electrodes for use in supercapacitors and as oxygen evolution catalysts. While the resultant capacitance was reasonably high at ?1200 F cm?3 (20 mV s?1), the catalytic performance was exceptional with currents of 10 mA cm?2 observed at overpotentials as low as 297 mV, close to the state of the art. ; This work was primarily funded by Science Foundation Ireland through the PI program (11/PI/1087). The research leading to these results has also received funding from the European Union Seventh Framework Program under grant agreement no. 604391 Graphene Flagship, the European Research Council (SEMANTICS) and the Science Foundation Ireland (SFI) funded centre AMBER (SFI/12/RC/2278)

OBJECTIVE Allergic rhinitis and allergic asthma are important chronic diseases posing serious public health issues in Australia with associated medical, economic, and societal burdens. Pollen are significant sources of clinically relevant outdoor aeroallergens, recognised as both a major trigger for, and cause of, allergic respiratory diseases. This study aimed to provide a national, and indeed international, perspective on the state of Australian pollen data using a large representative sample. METHODS Atmospheric grass pollen concentration is examined over a number of years within the period 1995 to 2013 for Brisbane, Canberra, Darwin, Hobart, Melbourne, and Sydney, including determination of the 'clinical' grass pollen season and grass pollen peak. RESULTS The results of this study describe, for the first time, a striking spatial and temporal variability in grass pollen seasons in Australia, with important implications for clinicians and public health professionals, and the Australian grass pollen-allergic community. CONCLUSIONS These results demonstrate that static pollen calendars are of limited utility and in some cases misleading. This study also highlights significant deficiencies and limitations in the existing Australian pollen monitoring and data. IMPLICATIONS Establishment of an Australian national pollen monitoring network would help facilitate advances in the clinical and public health management of the millions of Australians with asthma and allergic rhinitis. ; Funding support for the Working Group came from the Australian Centre for Ecological Analysis and Synthesis (ACEAS), Terrestrial Ecosystem Research Network (TERN), which is supported by the Australian Government through the National Collaborative Research Infrastructure Strategy and the Super Science Initiative. MSD provided additional independent untied co-sponsorship for the Working Group. Alison Jaggard has been assisted by the New South Wales Government through its Environmental Trust (project reference number 2011/RD/0049).

OBJECTIVE Allergic rhinitis and allergic asthma are important chronic diseases posing serious public health issues in Australia with associated medical, economic, and societal burdens. Pollen are significant sources of clinically relevant outdoor aeroallergens, recognised as both a major trigger for, and cause of, allergic respiratory diseases. This study aimed to provide a national, and indeed international, perspective on the state of Australian pollen data using a large representative sample. METHODS Atmospheric grass pollen concentration is examined over a number of years within the period 1995 to 2013 for Brisbane, Canberra, Darwin, Hobart, Melbourne, and Sydney, including determination of the 'clinical' grass pollen season and grass pollen peak. RESULTS The results of this study describe, for the first time, a striking spatial and temporal variability in grass pollen seasons in Australia, with important implications for clinicians and public health professionals, and the Australian grass pollen-allergic community. CONCLUSIONS These results demonstrate that static pollen calendars are of limited utility and in some cases misleading. This study also highlights significant deficiencies and limitations in the existing Australian pollen monitoring and data. IMPLICATIONS Establishment of an Australian national pollen monitoring network would help facilitate advances in the clinical and public health management of the millions of Australians with asthma and allergic rhinitis. ; Funding support for the Working Group came from the Australian Centre for Ecological Analysis and Synthesis (ACEAS), Terrestrial Ecosystem Research Network (TERN), which is supported by the Australian Government through the National Collaborative Research Infrastructure Strategy and the Super Science Initiative. MSD provided additional independent untied co-sponsorship for the Working Group. Alison Jaggard has been assisted by the New South Wales Government through its Environmental Trust (project reference number 2011/RD/0049).