Chromo-fluorogenic BODIPY-complexes for selective detection of V-type nerve agent surrogates
Two new Eu3+ and Au3+ BODIPY-complexes capable of chromofluorogenically detecting micromolar concentrations of V-type nerve agent surrogates by a simple displacement assay are described ; Financial support from the Spanish Government (Project MAT2012-38429-C04) and the Generalitat Valencia (Project PROMETEOII/2014/047) is gratefully acknowledged. A.B.B acknowledges the award of a pre-doctoral FPI fellowship. SCIE (Universidad de Valencia) is gratefully acknowledged for all the equipment employed. ; Barba Bon, A.; Costero Nieto, AM.; Gil Grau, S.; Sancenón Galarza, F.; Martínez Mañez, R. (2014). Chromo-fluorogenic BODIPY-complexes for selective detection of V-type nerve agent surrogates. Chemical Communications. 50(87):13289-13291. https://doi.org/10.1039/c4cc05945j ; S ; 13289 ; 13291 ; 50 ; 87 ; Kim, K., Tsay, O. G., Atwood, D. A., & Churchill, D. G. (2011). Destruction and Detection of Chemical Warfare Agents. Chemical Reviews, 111(9), 5345-5403. doi:10.1021/cr100193y ; S. M. Somani , Chemical Warfare Agent, Academic Press, San Diego, 1992 ; P. Taylor , in The Pharmacological Basis of Therapeutics, ed. J. G. Hardman, L. E. Limbird and A. G. Gilman, McGraw-Hill, New York, 10th edn, 2001, pp. 175–191 ; J. A. Vale , P.Rice and T. C.Marrs, in Chemical Warfare Agents: Toxicology and Treatment, ed. T. C. Marrs, R. L. Maynard and F. R. Sidell, John Wiley & Sons, Chichester, 2007 ; R. Gupta , Handbook of Toxicology of Chemical Warfare Agents, Academic Press, London, 2009 ; Wang, H., Wang, J., Choi, D., Tang, Z., Wu, H., & Lin, Y. (2009). EQCM immunoassay for phosphorylated acetylcholinesterase as a biomarker for organophosphate exposures based on selective zirconia adsorption and enzyme-catalytic precipitation. Biosensors and Bioelectronics, 24(8), 2377-2383. doi:10.1016/j.bios.2008.12.013 ; Steiner, W. E., Klopsch, S. J., English, W. A., Clowers, B. H., & Hill, H. H. (2005). Detection of a Chemical Warfare Agent Simulant in Various Aerosol Matrixes by Ion Mobility Time-of-Flight Mass Spectrometry. ...