Suchergebnisse

Society is facing serious challenges towards achieving highly efficient utilization of materials and devices. Magnetoactive lightweight materials, such as magnetorheological, magnetostrictive and magnetocaloric materials are attracting increasing interest once they allow a high number of applications such as energy generation, conversion, storage, sensing and actuation, as well as in the biomedical field. In this chapter, the latest research and development in multifunctional lightweight magnetorheological, magnetostrictive and magnetocaloric materials is summarized and discussed in the scope of different application areas. Furthermore, it will be also illustrated the unique functions of inorganic nanomaterials to improve performance of organic materials, as well as combination of the functions of nanomaterials into a device. Final remarks and future perspectives allow to look into a "magnetoactive crystal ball" aiming to foresee what will/should happen in this fascinating research field. ; The authors thank the FCT- Fundação para a Ciência e Tecnologia- for financial support in the framework of the Strategic Funding UID/FIS/04650/2019 and under project PTDC/BTM-MAT/28237/2017 and PTDC/EMD-EMD/28159/2017. P. Martins thanks FCT for the contract under the Stimulus of Scientific Employment, Individual Support – 2017 Call (CEECIND/03975/2017). The authors acknowledge funding by the Spanish Ministry of Economy and Competitiveness (MINECO) through the project MAT2016-76039-C4-3-R (AEI/FEDER, UE) and from the Basque Government Industry and Education Department under the ELKARTEK, HAZITEK and PIBA (PIBA-2018- 06) programs, respectively. Funding from the European Union's Horizon 2020 Programme for Research, ICT-02-2018 - Grant agreement no. 824339 – WEARPLEX is also ...

In the last decade, there have been significant advances on multifunctional materials development through additive manufacturing techniques, boosted by the Industry 4.0 and the Internet of Things revolution. However, in the particular case of the use of lightweight materials, the performance and multifunctionality is sometimes limited. After a short introduction, this chapter provides a comprehensive assessment of those limitations at the same time as the materials, techniques and challenges on the additive manufacturing of multifunctional materials. In the final paragraphs of this work, the future trends will be presented and discussed. ; FCT- Fundação para a Ciência e Tecnologia- for financial support in the framework of the Strategic Funding UID/FIS/04650/2020 and under project PTDC/BTM-MAT/28237/2017 and PTDC/EMD-EMD/28159/2017. P. Martins (CEECIND/03975/2017- assistant researcher contract Individual Support – 2017 Call) and V. Correia (DL57/2016 junior researcher contract) thank FCT for the contract under the Stimulus of Scientific Employment. The authors acknowledge funding from the Basque Government Industry and Education Department under the ELKARTEK, HAZITEK and PIBA (PIBA-2018-06) programs, respectively. Funding from the European Union's Horizon 2020 Programme for Research, ICT-02-2018 - Grant agreement no. 824339 – ...

Magnetic materials for magnetoelectric coupling are reported. After an introduction of magnetoelectric effect and materials, an historical on the main developments in this field are presented. Then, the main concepts related to multiferroic and magnetoelectric materials are introduced, together with the description of the main types of magnetoelectric materials and structures. Finally, the magnetic materials used the development of magnetoelectric composites are presented and discussed, highlighting their main physico-chemical characteristics and processing methods. In this way, a complete account on concepts, materials and methods is presented in this strongly evolving research field, with strong application potential in the areas of sensors and actuators, among others. ; FCT- Fundação para a Ciência e Tecnologia- for financial support in the framework of the Strategic Funding UID/FIS/04650/2020 and under projects PTDC/BTM-MAT/28237/2017 and PTDC/EMD-EMD/28159/2017. P.M., A.C.L. and N.P. also support from FCT (for the contract under the Stimulus of Scientific Employment, Individual Support – 2017 Call (CEECIND/03975/2017, for the SFRH/BD/132624/2017 and for the SFRH/BD/131729/2017 grant, respectively). Finally, the authors acknowledge funding by the Spanish State Research Agency (AEI) and the European Regional Development Fund (ERFD) through the project PID2019-106099RB-C43/AEI/10.13039/501100011033 and from the Basque Government Industry and Education Department under the ELKARTEK, HAZITEK and PIBA (PIBA-2018-06) ...

Magnetoelectric (ME) materials composed of magnetostrictive and piezoelectric phases have been the subject of decades of research due to their versatility and unique capability to couple the magnetic and electric properties of the matter. While these materials are often studied from a fundamental point of view, the 4.0 revolution (automation of traditional manufacturing and industrial practices, using modern smart technology) and the Internet of Things (IoT) context allows the perfect conditions for this type of materials being effectively/finally implemented in a variety of advanced applications. This review starts in the era of Rontgen and Curie and ends up in the present day, highlighting challenges/directions for the time to come. The main materials, configurations, ME coefficients, and processing techniques are reported. ; This research was funded by FCT—Fundação para a Ciência e Tecnologia: projects UID/FIS/04650/2019, PTDC/EEI-SII/5582/2014, PTDC/BTM-MAT/28237/2017 and PTDC/EMD-EMD/28159/2017 and grants CEECIND/03975/2017, SFRH/BD/132624/2017 and SFRH/BD/131729/2017; the SpanishState Research Agency (AEI) and the European Regional Development Fund (ERFD): project PID2019-106099RB-C43/AEI/10.13039/501100011033; Basque Government Industry and Education Departments:ELKARTEK, HAZITEK and PIBA (PIBA-2018-06) programs. ; The authors thank the FCT—Fundação para a Ciência e Tecnologia- for financial supportin the framework of the Strategic Funding UID/FIS/04650/2019 and under projects PTDC/EEI-SII/5582/2014, PTDC/BTM-MAT/28237/2017 and PTDC/EMD-EMD/28159/2017. P.M., A.C.L. and N.P. also support from FCT (forthe contract under the Stimulus of Scientific Employment, Individual Support—2017 Call (CEECIND/03975/2017, forthe SFRH/BD/132624/2017 and for the SFRH/BD/131729/2017 grant, respectively). Finally, the authors acknowledgefunding by the Spanish State Research Agency (AEI) and the European Regional Development Fund (ERFD)through the project PID2019-106099RB-C43/AEI/10.13039/501100011033.and from the Basque ...

Magnetic sensors are mandatory in a broad range of applications nowadays, being the increasing interest on such sensors mainly driven by the growing demand of materials required by Industry 4.0 and the Internet of Things concept. Optimized power consumption, reliability, flexibility, versatility, lightweight and low-temperature fabrication are some of the technological requirements in which the scientific community is focusing efforts. Aiming to positively respond to those challenges, this work reports magnetic proximity sensors based on magnetoelectric (ME) polyvinylidene fluoride (PVDF)/Metglas composites and an excitation-printed coil. The proposed magnetic proximity sensor shows a maximum resonant ME coefficient (α) of 50.2 Vcm −1 Oe −1 , an AC linear response (R 2 = 0.997) and a maximum voltage output of 362 mV, which suggests suitability for proximity-sensing applications in the areas of aerospace, automotive, positioning, machine safety, recreation and advertising panels, among others. ; This research was funded by CT- Fundação para a Ciência e Tecnologia in the framework of the Strategic Funding UID/FIS/04650/2019 and under projects PTDC/EEI-SII/5582/2014, PTDC/BTM-MAT/28237/2017 and PTDC/EMD-EMD/28159/2017. A.C.L. and N.P. acknowledge also support from FCT (SFRH/BD/132624/2017 and SFRH/BD/131729/2017 grants respectively). P. Martins also thanks FCT for the contract under the Stimulus of Scientific Employment, Individual Support—2017 Call (CEECIND/03975/2017). Finally, the authors acknowledge funding by the Spanish Ministry of Economy and Competitiveness (MINECO) through the project MAT2016-76039-C4-3-R (AEI/FEDER, UE) and from the Basque Government Industry and Education Department under the ELKARTEK, HAZITEK and PIBA (PIBA-2018-06) programs, ...

Abstract: In order to obtain a wide-range magnetoelectric (ME) response on a ME nanocomposite that matches industry requirements, Tb0.3Dy0.7Fe1.92 (Terfenol-D)/CoFe2O4/P(VDF-TrFE) flexible films were produced by solvent casting technique and their morphologic, piezoelectric, magnetic and magnetoelectric properties investigated. The obtained composites revealed a high piezoelectric response (≈-18 pC.N-1) that is independent of the weight ratio between the fillers. In turn, the magnetic properties of the composites were influenced by the composite composition. It was found that the magnetization saturation values decreased with increasing CoFe2O4 content (from 18.5 to 13.3 emu.g-1) while the magnetization and coercive field values increased (from 3.7 to 5.5 emu.g-1 and from 355.7 to 1225.2 Oe, respectively) with increasing CoFe2O4 content. Additionally, those films showed a wide-range dual-peak ME response at room temperature with the ME coefficient increasing with weight content of Terfenol-D, from 18.6 mV.cm-1.Oe-1 to 42.3 mV.cm-1.Oe-1. ; FCT-Fundação para a Ciência e Tecnologia—for financial support in the framework of the Strategic Funding UID/FIS/04650/2013 and under project PTDC/EEI-SII/5582/2014. Pedro Martins, Silvia Reis and Marco Silva also acknowledge support from FCT (SFRH/BPD/96227/2013, SFRH/BDE/406 and SFRH/BD/70303/2010 grants, respectively). The authors acknowledge funding by the Spanish Ministry of Economy and Competitiveness (MINECO) through the project MAT2016-76039-C4-3-R (AEI/FEDER, UE) (including the FEDER financial support). Financial support from the Basque Government Industry Department under the ELKARTEK program is also acknowledged. The authors thank INL, International Iberian Nanotechnology Laboratory, Braga, Portugal, for offering access to their instruments and expertise ...

Among magnetoelectric (ME) heterostructures, ME laminates of the type Metglas-like / PVDF (magnetostrictive+piezoelectric constituents) have shown the highest induced ME voltages, usually detected at the magnetoelastic resonance of the magnetostrictive constituent. This ME coupling happens because of the high cross-correlation coupling between magnetostrictive and piezoelectric material, and is usually associated with a promising application scenario for sensors or actuators. In this work we detail the basis of the operation of such devices, as well as some arising questions (as size effects) concerning their best performance. Also, some examples of their use as very sensitive magnetic fields sensors or innovative energy harvesting devices will be reviewed. At the end, the challenges, future perspectives and technical difficulties that will determine the success of ME composites for sensor applications are discussed. ; J.G., A.L. and J.M.B. would like to thank the financial support from the Basque Government under ACTIMAT and MICRO4FAB projects (Etortek program) and Research Groups IT711-13 project. A. Lasheras wants to thank the Basque Government for financial support under FPI Grant. Technical and human support provided by SGIker (UPV/EHU, MICINN, GV/EJ, ESF) is gratefully acknowledged. P.M., N.P. and S. L.-M. thank the Portuguese Fundação para a Ciência e Tecnologia (FCT) for financial Sensors 2017, 13 19 support under Strategic Funding UID/FIS/04650/2013 and project PTDC/EEI-SII/5582/2014, including FEDER funds, UE. P. Martins acknowledges also support from FCT (SFRH/BPD/96227/2013 grant). Financial support from the Spanish Ministry of Economy and Competitiveness (MINECO) through the project MAT2016-76039-C4-3-R (AEI/FEDER, UE) (including the FEDER financial support) is also acknowledged ...

In this work, we explore the addition of Ti ribbons on the racetrack of a Zr target to prepare Zr-O-N films including Ti, by reactive magnetron sputtering with a mixture of N2 and O2 as reactive gases. This approach is simple and not invasive, it avoids the modification of the target and minimizes its contamination. These films were compared in terms of chemical composition, density, film growth and crystallographic structure with others prepared in identical conditions without Ti ribbons. In addition, the composition and density of the films were correlated with crystallographic references from literature. The color and electrical properties of the films were evaluated as well. It was observed that poisoning of the Zr target is promoted by the increase of the N2 + O2 flow and the reduction of magnetron current, but it is retarded by the introduction of the Ti ribbons. This effect was particularly remarkable at lower target current, since the sputtering is confined in areas nearer to the racetrack, where the Ti ribbons are located. To account for the poisoning of the target and compare it among the different samples, a 'poisoning parameter' was defined, using a combination of the chemical composition of the films and the deposition rates. The color and electrical properties of the films correlate surprisingly well with their oxygen-to-metal ratio, while the concentration of N does not seem to play any significant role. ; The financial support of Portuguese Foundation of Science and Technology (FCT), under the projects IF/00671/2013, M-ERA-NET2/0012/2016, and Strategic Funding UIDB/04650/2020 are gratefully acknowledged. The financial support from the Basque Government Industry Department under the ELKARTEK program is also ...

A poly(vinylidene fluoride) (PVDF) and its copolymers are polymers that, in specific crystalline phases, show high dielectric and piezoelectric values, excellent mechanical behavior and good thermal and chemical stability, suitable for many applications from the biomedical area to energy devices. This chapter introduces the main properties, processability and polymorphism of PVDF. Further, the recent advances in the applications based on those materials are presented and discussed. Thus, it shown the key role of PVDF and its copolymers as smart and multifunctional material, expanding the limits of polymer-based technologies. ; FCT (Fundação para a Ciência e Tecnologia) for financial support under the framework of Strategic Funding grants UID/FIS/04650/2019, and UID/QUI/0686/2019 and project PTDC/FIS-MAC/28157/2017, PTDC/BTMMAT/28237/2017, PTDC/EMD-EMD/28159/2017. The author also thanks the FCT for financial support under grant SFRH/BPD/112547/2015 (C.M.C.), SFRH/BPD/98109/2013 (V.F.C.), SFRH/BD/140698/2018 (R.B.P.), SFRH/BPD/96227/2013 (P.M.), SFRH/BPD/121526/2016 (D.M.C.), SFRH/BPD/97739/2013 (V. C.), SFRH/BPD/90870/2012 (C.R.). Financial support from the Spanish Ministry of Economy and Competitiveness (MINECO) through project MAT2016-76039-C4-3-R (AEI/FEDER, UE) (including FEDER financial support) and from the Basque Government Industry and Education Departments under the ELKARTEK, HAZITEK and PIBA ...