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Abstract. Temporal clustering structures were identified and quantified in fire sequences recorded from 1980 to 2005 in Continental Portugal, by using the Allan Factor statistics, a statistical tool suited to reveal clustering behaviour in point processes. The obtained results show the presence of daily and annual periodicities, superimposed onto a scaling behaviour, which features the sequence of wildfires as a fractal time process with a rather high degree of time-clusterization of the events.

Medical family therapy represents the maturity of the family therapy's field emphasizing the collaboration between family therapists and medical providers. This theoretical study describes the evolution of this new discipline from its conception in the biopsychosocial model, to our days, starting with biopsychosocial oriented family theories, family centered medical care and culminating with the creation of medical family therapy. Biopsychosocial oriented family theory emphasized the relationship between health and psychosocial dimensions. Family Oriented Primary Care provided the physician with the counseling skills necessary to address the patient emotional needs regarding medical problems. Finally, Medical Family Therapy applies family therapy techniques in families with specific health problems and its focus is in advocating for patients, family members and health care professionals in integrated health care. Medical family therapy as a new discipline represents the development of family therapy in the practice of biopsychosoical medicine both theoretically and in health care delivery. This paper also addresses political issues that medical family therapy has to face regarding health care in particular the use of the DSM-IV diagnosis. ; La terapia familiar médica representa el desarrollo del campo de la terapia familiar que tiene como objetivo la colaboración entre terapeutas familiares y profesionales de la salud. Este estudio teórico destaca la evolución de esta reciente disciplina desde su concepción en el modelo biopsicosocial hasta la actualidad, pasando por las teorías familiares con base biopsicosocial, cuidados médicos centrados en la familia y culminando con la creación de la terapia familiar médica. Las teorías familiares con base biopsicosocial destacan la relación entre la salud y las dimensiones psicosociales. Los Cuidados Médicos Centrados en la Familia facilitan al médico las competencias de consulta necesarias para hacer frente a las necesidades emocionales del paciente con respecto a los ...

Microbial electrochemical technologies (METs) are promising for sustainable applications. Recently, electron storage during intermittent operation of electroactive biofilms (EABs) has been shown to play an important role in power output and electron efficiencies. Insights into electron storage mechanisms, and the conditions under which these occur, are essential to improve microbial electrochemical conversions and to optimize biotechnological processes. Here, we discuss the two main mechanisms for electron storage in EABs: storage in the form of reduced redox active components in the electron transport chain and in the form of polymers. We review electron storage in EABs and in other microorganisms and will discuss how the mechanisms of electron storage can be influenced. ; This work is part of the research program Vidi (with project number 17516), which is (partly) financed by the Dutch Research Council (NWO). The research was performed in cooperation with Wetsus, the European Centre of Excellence for Sustainable Water Technology. Wetsus is cofunded by the Dutch Ministry of Economic Affairs and Ministry of Infrastructure and Environment, the European Union Regional Development Fund, the Province of Fryslân, and the Northern Netherlands Provinces. The authors would like to thank the participants of the research theme 'Resource Recovery' for the fruitful discussions and their financial support. The authors also acknowledge the financial support given by the Portuguese Foundation for Science and Technology (FCT) under the scope of the strategic funding of UIDB/04469/2020 unit and BioTecNorte operation (NORTE-01-0145-FEDER-000004) funded by the European Regional Development Fund under the scope of Norte2020 – Programa Operacional Regional do Norte. ...

Abstract. The topographic characteristics and spatial climatic diversity are significant in the South of continental Portugal where the rainfall regime is typically Mediterranean. Direct sequential cosimulation is proposed for mapping an extreme precipitation index in southern Portugal using elevation as auxiliary information. The analysed index (R5D) can be considered a flood indicator because it provides a measure of medium-term precipitation total. The methodology accounts for local data variability and incorporates space-time models that allow capturing long-term trends of extreme precipitation, and local changes in the relationship between elevation and extreme precipitation through time. Annual gridded datasets of the flood indicator are produced from 1940 to 1999 on 800 m×800 m grids by using the space-time relationship between elevation and the index. Uncertainty evaluations of the proposed scenarios are also produced for each year. The results indicate that the relationship between elevation and extreme precipitation varies locally and has decreased through time over the study region. In wetter years the flood indicator exhibits the highest values in mountainous regions of the South, while in drier years the spatial pattern of extreme precipitation has much less variability over the study region. The uncertainty of extreme precipitation estimates also varies in time and space, and in earlier decades is strongly dependent on the density of the monitoring stations network. The produced maps will be useful in regional and local studies related to climate change, desertification, land and water resources management, hydrological modelling, and flood mitigation planning.

Due to their large-scale production and extensive application, dyes have turned serious pollutants when improperly handled and disposed, creating grave public health and environmental problems. One of the problems that textile industry is facing is related with the incomplete exhaustion of dyes onto textile fibres from an aqueous dyeing process, and the need to implement innovative and sustainable effluent treatment methods to remove colour. Additionally, legislation on the limits of colour discharge has turn increasingly rigid. Biological treatment systems have been shown as promising technologies. The main limiting factor of the reductive transformations by anaerobic sludge is the electron transfer, a slow process. This limitation can be overcome by making use of redox mediators, which are compounds that accelerate the electron transfer from a primary electron donor to a terminal electron acceptor, to speed up the process. Activated carbon (AC) has been shown as a feasible redox mediator. Samples of microporous thermal treated AC (ACH2) and mesoporous carbons: Xerogels (CXA, CXB) and Carbon nanotubes (CNT) were tested on azo dye and textile wastewater biodegradation. ∼85% Mordant Yellow 10 (MY10) and 70% of Reactive Red 120 (RR120) colour removal was obtained with all the carbon materials. Acid Orange 10 (AO10) is not biodegraded in the absence of Carbon Materials, but with CXB and CNT a 98% of colour removal was achieved. For MY10 and RR120, rates increased in the order: control < ACH2< CXA < CXB < CNT. HPLC analysis confirmed the reduction of dyes with the formation of corresponding aromatic amines. The effect of CNT was also observed in the biological treatment of real textile wastewaters. ; R. Pereira holds a fellowship (SFRH/BD/72388/2010) and L. Pereira holds a Pos-Doc fellowship (SFRH/BPD/80941/2011) from Fundacao para a Ciencia e ...

Co-fermentation of garden waste (GW) and food waste (FW) was assessed in a two-stage process coupling hyperthermophilic dark-fermentation and mesophilic anaerobic digestion (AD). In the first stage, biohydrogen production from individual substrates was tested at different volatile solids (VS) concentrations, using a pure culture of Caldicellulosiruptor saccharolyticus as inoculum. FW concentrations (in VS) above 2.9 g L-1 caused a lag phase of 5 days on biohydrogen production. No lag phase was observed for GW concentrations up to 25.6 g L-1. In the co-fermentation experiments, the highest hydrogen yield (46±1 L kg-1) was achieved for GW:FW 90:10% (w/w). In the second stage, a biomethane yield of 682±14 L kg-1 was obtained using the end-products of GW:FW 90:10% co-fermentation. The energy generation predictable from co-fermentation and AD of GW:FW 90:10% is 0.5 MJ kg-1 and 24.4 MJ kg-1, respectively, which represents an interesting alternative for valorisation of wastes produced locally in communities. ; This study was supported by the Portuguese Foundation for Science and Technology (FCT) under the scope of the strategic funding of UID/BIO/04469/2013 unit and COMPETE 2020 (POCI-01-0145-FEDER006684), Project SAICTPAC/0040/2015 (POCI-01-0145-FEDER016403) and BioTecNorte operation (NORTE-01-0145-FEDER-000004) funded by the European Regional Development Fund under the scope of Norte2020– Programa Operacional Regional do Norte. The authors also acknowledge the financial support of FCT and European Social Fund through the grant attributed to A.A. Abreu (SFRH/BPD/82000/2011). Research of A.J. Cavaleiro was supported by the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement No 323009. ...

Supplementary data associated with this article can be found, in the online version, at: http://dx.doi.org/10.1016/j.cej.2016.03.148. ; Phosphorus recycling and recovery has received special attention due to its non-replaceable and non-renewability. Phosphorus recovery from human urine in the form of struvite crystals is a potential alternative source. In this work, the efficiency of struvite precipitation from source separated human urine and struvite crystals size were analyzed using three different Mg2+ sources (MgCl2, Mg(OH)2 and MgO), individually evaluated using a statistical design of experiments to assess the combined effect of Mg2+:P molar ratio (1:1, 1.5:1 and 2:1) and stirring speed (30, 45 and 60 rpm). Formation of struvite crystals was confirmed by X-ray Diffraction (XRD) and scanning electron microscopy (SEM) with an energy dispersive spectrometer (EDS). Using the optimal conditions determined, MgO as Mg2+ source at 2:1 molar ratio and a stirring speed of 30 rpm, 99% of P was recovered as struvite crystals with a size of 50 to 100 m. ; This project has received funding from the European Union's Seventh Programme for research, technological development and demonstration under grant agreement No. 308535. The authors also acknowledge the Portuguese Foundation for Science and Technology (FCT) under the scope of the strategic funding of UID/BIO/04469/2013 unit, COMPETE 2020 (POCI-01-0145-FEDER-006684) and the project RECI/BBB-EBI/0179/2012 ...

Although mercury bio-amplifies through the food chain and accumulates in top predators, mercury concentrations in tissues of the wandering albatross are greater than in any other vertebrate, including closely related species. In order to explore the alternative explanations for this pattern, we measured total mercury concentrations in feathers, plasma and blood cells of wandering albatrosses of known age, sex and breeding status sampled at South Georgia. Mercury concentrations were low in feathers and blood components of chicks, and higher in the feathers of young pre-breeders than in feathers or blood of older pre-breeders and breeding adults. There was no effect of sex on mercury concentrations in the feathers of pre-breeders or breeding adults, whereas levels were significantly higher in blood cells of breeding females than males. The high feather mercury concentrations of young pre-breeders compared with older birds suggest an increase in moult frequency as birds approach maturity. ; This work was supported by the Portuguese Foundation for the Science and Technology (FCT) through a PhD grant to Sílvia Tavares (SFRH/BD/48908/2008),co-funded by the European Social Fund and Portuguese Government National Funds, and through the project POLAR. This paper represents a contribution to the British Antarctic Survey Ecosystems Programme, the national program PROPOLAR and the international programs of ICED and SCAR AnT-ERA.

Abstract. We focus here on a mainland Continental Portuguese Rural Fire Database (PRFD) that includes 450 000 fires, the largest such database in Europe in terms of total number of recorded fires in the 1980–2005 period. In this work, we (a) list the most important factors for triggering and controlling the fire regime in mainland Continental Portugal, (b) describe the dataset's production, (c) discuss procedures adopted to identify and correct different fire data inconsistencies, creating a modified PRFD which we use here and make available as Supplement, (d) explore some basic temporal and completeness properties of the data. We find that the dataset's minimum measured burnt areas have changed with time between AF = 0.1 ha (1980–1990), AF = 0.01 ha (1991–1992), and AF = 0.001 ha (1992–2005), with varying degrees of completeness down to these values. These changes in minimum area measured are responsible for greater numbers of fires being recorded. A relatively small number of large fires in the PRFD are responsible for the majority of the burnt area. For example, fires with AF > 100 ha represent about 1% of all fire records but 75% of total burnt area. Finally, we consider for each Continental Portugal district and for the 26-yr period, the total number of rural fires and area burnt in forests and shrublands, each normalized by district areas. We find that the highest numbers of fires per unit area are in highly populated districts, and that the largest fraction of burnt area is in forested areas, coinciding with large parcels of continuous forests (predominantly rural and moderately urban areas).

Abstract. Due to its economic and nutritional value, the world production of chestnuts is increasing as new stands are being planted in various regions of the world. This work focuses on the relation between weather and annual chestnut production to model the role of weather, to assess the impacts of climate change and to identify appropriate locations for new groves. The exploratory analysis of chestnut production time series and the striking increase of production area have motivated the use for chestnut productivity. A large set of meteorological variables and remote sensing indices were computed and their role on chestnut productivity evaluated with composite and correlation analyses. These results allow for the identification of the variables cluster with a high correlation and impact on chestnut production. Then, different selection methods were used to develop multiple regression models able to explain a considerable fraction of productivity variance: (i) a simulation model (R2-value = 87%) based on the winter and summer temperature and on spring and summer precipitation variables; and, (ii) a model to predict yearly chestnut productivity (R2-value of 63%) with five months in advance, combining meteorological variables and NDVI. Goodness of fit statistic, cross validation and residual analysis demonstrate the model's quality, usefulness and consistency of obtained results.