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In the present study, we evaluated the concentrations of PAHs in 3 PM fractions (10, 2.5 and 1) collected in the surroundings of a cement plant located in Barcelona. PAH content and speciation were developed for the three fractions to elucidate their distribution among different sizes. Complementarily, the human health risks associated to the PAH exposure were risks by considering the daily activity pattern of an average adult living in of Barcelona (Spain). ; Financial support was received by the Spanish Ministry of Economy and Competitiveness (MINECO), through the project CTM2012-32778. F. Sánchez-Soberón received a doctoral scholarship as part of the project above mentioned. We also want to thank the European Union Seventh Framework Program for the funding received through the HEALS project (grant agreement No. 603946). ; Peer reviewed

Open Access article, published by EDP Sciences, under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. ; Context. The tenuous nitrogen (N2) atmosphere on Pluto undergoes strong seasonal effects due to high obliquity and orbital eccentricity, and has recently (July 2015) been observed by the New Horizons spacecraft. Aims. The main goals of this study are (i) to construct a well calibrated record of the seasonal evolution of surface pressure on Pluto and (ii) to constrain the structure of the lower atmosphere using a central flash observed in 2015. Methods. Eleven stellar occultations by Pluto observed between 2002 and 2016 are used to retrieve atmospheric profiles (density, pressure, temperature) between altitude levels of ∼5 and ∼380 km (i.e. pressures from ∼10 μbar to 10 nbar). Results. (i) Pressure has suffered a monotonic increase from 1988 to 2016, that is compared to a seasonal volatile transport model, from which tight constraints on a combination of albedo and emissivity of N2 ice are derived. (ii) A central flash observed on 2015 June 29 is consistent with New Horizons REX profiles, provided that (a) large diurnal temperature variations (not expected by current models) occur over Sputnik Planitia; and/or (b) hazes with tangential optical depth of ∼0.3 are present at 4-7 km altitude levels; and/or (c) the nominal REX density values are overestimated by an implausibly large factor of ∼20%; and/or (d) higher terrains block part of the flash in the Charon facing hemisphere.© E. Meza et al. 2019 ; The work leading to these results has received funding from the European Research Council under the European Community's H2020 2014-2020 ERC Grant Agreement no 669416 >Lucky Star>. E.M. thanks support from Concytec-Fondecyt-PE and GA, FC-UNI for providing support during the 2012 July 18 occultation. B.S. thanks S. Para for partly supporting this research though a donation, J. P. Beaulieu for helping us accessing to the Hobart Observatory facilities and B. Warner, B. L. Gary, C. Erickson, H. Reitsema, L. Albert, P. J. Merritt, T. Hall, W. J. Romanishin, Y. J. Choi for providing data during the 2007 March 18 occultation. M.A. thanks CNPq (Grants 427700/2018-3, 310683/2017-3 and 473002/2013-2) and FAPERJ (Grant E-26/111.488/2013). J.L.O. thanks support from grant AYA2017-89637-R. P.S.S. acknowledges financial support from the European Union's Horizon 2020 Research and Innovation Programme, under Grant Agreement no 687378, as part of the project > Small Bodies Near and Far> (SBNAF). J.L.O., R.D., P.S.S. and N.M. acknowledge financial support from the State Agency for Research of the Spanish MCIU through the > Center of Excellence Severo Ochoa> award for the Instituto de Astrofisica de Andalucia (SEV-2017-0709). F.B.R. acknowledges CNPq support process 309578/2017-5. G.B.R. thanks support from the grant CAPES-FAPERJ/PAPDRJ (E26/203.173/2016). J.I.B.C. acknowledges CNPq grant 308150/2016-3. R.V.M. thanks the grants: CNPq-304544/2017-5, 401903/2016-8, and Faperj: PAPDRJ-45/2013 and E-26/203.026/2015. B.M. thanks the CAPES/Cofecub-394/2016-05 grant and CAPES/Brazil -Finance Code 001. B.M. and A.R.G.J. were financed in part by the Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior -Brasil (CAPES) -Finance Code 001. TRAPPIST-North is a project funded by the University of Liege, in collaboration with Cadi Ayyad University of Marrakech (Morocco). TRAPPIST-South is a project funded by the Belgian Fonds (National) de la Recherche Scientifique (F.R.S.-FNRS) under grant FRFC 2.5.594.09. F, with the participation of the Swiss National Science Foundation (FNS/SNSF). VSD, SPL, TRM and ULTRACAM are all supported by the STFC. K.G. acknowledges help from the team of Archenhold-Observatory, Berlin, and A. R. thanks G. Roman (Granada) for help during the observation of the 2016 July 19 occultation. A.J.C.T. acknowledges support from the Spanish Ministry Project AYA2015-71718-R (including EU funds). ; Peer Reviewed