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[EN] This critical review is focused on examples reported from 1947 to 2010 related to the design of chromo-fluorogenic chemosensors and reagents for explosives (141 references). © 2012 The Royal Society of Chemistry. ; Financial support from the Spanish Government (project MAT2009-14564-C04) and the Generalitat Valencia (project PROMETEO/2009/016) is gratefully acknowledged. Y.S. is grateful to the Spanish Ministry of Science and Innovation for her grant. ; Salinas Soler, Y.; Martínez Mañez, R.; Marcos Martínez, MD.; Sancenón Galarza, F.; Costero Nieto, AM.; Parra Álvarez, M.; Gil Grau, S. (2012). Optical chemosensors and reagents to detect explosives. Chemical Society Reviews. 41(3):1261-1296. https://doi.org/10.1039/c1cs15173h ; S ; 1261 ; 1296 ; 41 ; 3 ; Furton, K. (2001). The scientific foundation and efficacy of the use of canines as chemical detectors for explosives. Talanta, 54(3), 487-500. doi:10.1016/s0039-9140(00)00546-4 ; H�kansson, K., Coorey, R. V., Zubarev, R. A., Talrose, V. L., & H�kansson, P. (2000). Low-mass ions observed in plasma desorption mass spectrometry of high explosives. Journal of Mass Spectrometry, 35(3), 337-346. doi:10.1002/(sici)1096-9888(200003)35:3 337::aid-jms940>3.0.co;2-7 ; Walsh, M. (2001). Determination of nitroaromatic, nitramine, and nitrate ester explosives in soil by gas chromatography and an electron capture detector. Talanta, 54(3), 427-438. doi:10.1016/s0039-9140(00)00541-5 ; Sylvia, J. M., Janni, J. A., Klein, J. D., & Spencer, K. M. (2000). Surface-Enhanced Raman Detection of 2,4-Dinitrotoluene Impurity Vapor as a Marker To Locate Landmines. Analytical Chemistry, 72(23), 5834-5840. doi:10.1021/ac0006573 ; Yinon, J. (1982). Mass spectrometry of explosives: Nitro compounds, nitrate esters, and nitramines. Mass Spectrometry Reviews, 1(3), 257-307. doi:10.1002/mas.1280010304 ; Mathurin, J. C., Faye, T., Brunot, A., Tabet, J. C., Wells, G., & Fuché, C. (2000). High-Pressure Ion Source Combined with an In-Axis Ion Trap Mass Spectrometer. 1. ...

[EN] Mesoporous silica nanoparticles loaded with fluorescein and capped by a pseudorotaxane, formed between a naphthalene derivative and cyclobis(paraquat-p-phenylene) (CBPQT(4+)), were used for the selective and sensitive fluorogenic detection of 3,4-methylenedioxy-methamphetamine (MDMA). ; The authors acknowledge the financial support from the Spanish Government (projects MAT2015-64139-C4-1-R and AGL2015-70235-C2-2-R) and the Generalitat Valenciana (project GVA/2014/13). B. L-T. is grateful to the Ministerio de Economia y Competitividad for her PhD grant. A. B. thanks the Spanish Government for the financial support "Juan de la CiervaIncorporacion'' (IJCI-2014-21534). J. O. J. thanks The Danish Natural Science Research Council (FNU, project no. 11-106744) and the Villum Foundation for financial support. ; Lozano-Torres, B.; Pascual, L.; Bernardos Bau, A.; Marcos Martínez, MD.; Jeppesen, JO.; Salinas Soler, Y.; Martínez-Máñez, R. (2017). Pseudorotaxane capped mesoporous silica nanoparticles for 3,4-methylenedioxymethamphetamine (MDMA) detection in water. Chemical Communications. 53(25):3559-3562. https://doi.org/10.1039/c7cc00186j ; S ; 3559 ; 3562 ; 53 ; 25 ; McLELLAN, A. T., LUBORSKY, L., WOODY, G. E., & O??BRIEN, C. P. (1980). An Improved Diagnostic Evaluation Instrument for Substance Abuse Patients. The Journal of Nervous and Mental Disease, 168(1), 26-33. doi:10.1097/00005053-198001000-00006 ; Moonzwe, L. S., Schensul, J. J., & Kostick, K. M. (2011). The Role of MDMA (Ecstasy) in Coping with Negative Life Situations Among Urban Young Adults. Journal of Psychoactive Drugs, 43(3), 199-210. doi:10.1080/02791072.2011.605671 ; Meyer, J. (2013). 3,4-methylenedioxymethamphetamine (MDMA): current perspectives. Substance Abuse and Rehabilitation, 83. doi:10.2147/sar.s37258 ; Greene, S. L., Kerr, F., & Braitberg, G. (2008). Review article: Amphetamines and related drugs of abuse. Emergency Medicine Australasia, 20(5), 391-402. doi:10.1111/j.1742-6723.2008.01114.x ; Cumba, L. R., Smith, J. P., Zuway, K. ...

3559 3562 53 25 ; S ; [EN] Mesoporous silica nanoparticles loaded with fluorescein and capped by a pseudorotaxane, formed between a naphthalene derivative and cyclobis(paraquat-p-phenylene) (CBPQT(4+)), were used for the selective and sensitive fluorogenic detection of 3,4-methylenedioxy-methamphetamine (MDMA). The authors acknowledge the financial support from the Spanish Government (projects MAT2015-64139-C4-1-R and AGL2015-70235-C2-2-R) and the Generalitat Valenciana (project GVA/2014/13). B. L-T. is grateful to the Ministerio de Economia y Competitividad for her PhD grant. A. B. thanks the Spanish Government for the financial support "Juan de la CiervaIncorporacion'' (IJCI-2014-21534). J. O. J. thanks The Danish Natural Science Research Council (FNU, project no. 11-106744) and the Villum Foundation for financial support. Lozano-Torres, B.; Pascual, L.; Bernardos Bau, A.; Marcos Martínez, MD.; Jeppesen, JO.; Salinas Soler, Y.; Martínez-Máñez, R. (2017). Pseudorotaxane capped mesoporous silica nanoparticles for 3,4-methylenedioxymethamphetamine (MDMA) detection in water. Chemical Communications. 53(25):3559-3562. https://doi.org/10.1039/c7cc00186j McLELLAN, A. T., LUBORSKY, L., WOODY, G. E., & O??BRIEN, C. P. (1980). An Improved Diagnostic Evaluation Instrument for Substance Abuse Patients. The Journal of Nervous and Mental Disease, 168(1), 26-33. doi:10.1097/00005053-198001000-00006 Moonzwe, L. S., Schensul, J. J., & Kostick, K. M. (2011). The Role of MDMA (Ecstasy) in Coping with Negative Life Situations Among Urban Young Adults. Journal of Psychoactive Drugs, 43(3), 199-210. doi:10.1080/02791072.2011.605671 Meyer, J. (2013). 3,4-methylenedioxymethamphetamine (MDMA): current perspectives. Substance Abuse and Rehabilitation, 83. doi:10.2147/sar.s37258 Greene, S. L., Kerr, F., & Braitberg, G. (2008). Review article: Amphetamines and related drugs of abuse. Emergency Medicine Australasia, 20(5), 391-402. doi:10.1111/j.1742-6723.2008.01114.x Cumba, L. R., Smith, J. P., Zuway, K. Y., Sutcliffe, O. B., ...

[EN] A hybrid capped mesoporous material, which was selectively opened in the presence of Tetryl and TNT, has been synthesised and used for the fluorogenic recognition of these nitroaromatic explosives. ; Financial support from the Spanish Government (project MAT2012-38429-C04-01) and the Generalitat Valencia (project PROMETEO/2009/016) is gratefully acknowledged. Y.S. and E.P. are grateful to the Spanish Ministry of Science and Innovation for their grants. A. A. also thanks the Generalitat Valenciana for his Santiago Grisolia fellowship. ; Salinas Soler, Y.; Agostini, A.; Pérez Esteve, E.; Martínez Mañez, R.; Sancenón Galarza, F.; Marcos Martínez, MD.; Soto Camino, J. (2013). Fluorogenic detection of Tetryl and TNT explosives using nanoscopic-capped mesoporous hybrid materials. Journal of Materials Chemistry. 1(11):3561-3564. https://doi.org/10.1039/C3TA01438J ; S ; 3561 ; 3564 ; 1 ; 11 ; Singh, S. (2007). Sensors—An effective approach for the detection of explosives. Journal of Hazardous Materials, 144(1-2), 15-28. doi:10.1016/j.jhazmat.2007.02.018 ; Schulte-Ladbeck, R., Vogel, M., & Karst, U. (2006). Recent methods for the determination of peroxide-based explosives. Analytical and Bioanalytical Chemistry, 386(3), 559-565. doi:10.1007/s00216-006-0579-y ; Smith, R. G., D'Souza, N., & Nicklin, S. (2008). A review of biosensors and biologically-inspired systems for explosives detection. The Analyst, 133(5), 571. doi:10.1039/b717933m ; Moore, D. S. (2004). Instrumentation for trace detection of high explosives. Review of Scientific Instruments, 75(8), 2499-2512. doi:10.1063/1.1771493 ; H�kansson, K., Coorey, R. V., Zubarev, R. A., Talrose, V. L., & H�kansson, P. (2000). Low-mass ions observed in plasma desorption mass spectrometry of high explosives. Journal of Mass Spectrometry, 35(3), 337-346. doi:10.1002/(sici)1096-9888(200003)35:3 337::aid-jms940>3.0.co;2-7 ; Wallis, E., Griffin, T. M., Popkie, Jr., N., Eagan, M. A., McAtee, R. F., Vrazel, D., & McKinly, J. (2005). Instrument response ...