Suchergebnisse

Context. An astronomical survey of interstellar molecular clouds needs a previous analysis of the spectra in the microwave and sub-mm energy range of organic molecules to be able to identify them. We obtained very accurate spectroscopic constants in a comprehensive laboratory analysis of rotational spectra. These constants can be used to predict the transitions frequencies very precisely that were not measured in the laboratory. Aims. We present the experimental study and its theoretical analysis for two 13C-methyl formate isotopologues to detect these two isotopologues for the first time in their excited torsional states, which lie at 130 cm-1 (200 K) in Orion-KL. Methods. New spectra of HCOO13CH3 (13C2) methyl formate were recorded with the mm- and submm-wave spectrometer in Lille from 50 to 940 GHz. A global fit for vt = 0 and 1 was accomplished with the BELGI program to reproduce the experimental spectra with greater accuracy. Results. We analysed 5728 and 2881 new lines for vt = 0 and 1 for HCOO13CH3. These new lines were globally fitted with 846 previously published lines for vt = 0. In consequence, 52 parameters of the RAM Hamiltonian were accurately determined and the value of the barrier height (V3 = 369.93168(395) cm-1) was improved. We report the detection of the first excited torsional states (vt = 1) in Orion-KL for the 13C2 and 13C1 methyl formate based on the present analysis and previously published data. We provide column densities, isotopic abundances, and vibrational temperatures for these species. Conclusions. Following this work, accurate prediction can be provided. This permits detecting 135 features of the first excited torsional states of 13C-methyl formate isotopologues in Orion-KL in the 80−280 GHz frequency range, without missing lines. ; M.C. acknowledges the financial support the Spanish Government through grant FIS2011-28738-C02-02, and by a joint project within the framework of a CNRS (France) and CSIC (Spain) agreement (Code No.: 2011 FR0018). J.C., A.L. and B.T. thank the Spanish MINECO for funding support from grants CSD2009-00038, AYA2009-07304, and AYA2012-32032. This work was supported by the Centre National d'Etudes Spatiales (CNES) and the Action sur Projets de l'INSU, "Physique et Chimie du Milieu Interstellaire". This work was also performed under the ANR-08-BLAN-0054.

Context. Astronomical survey of interstellar molecular clouds needs a previous analysis of the spectra in the microwave and sub-mm energy range to be able to identify them. We obtained very accurate spectroscopic constants in a comprehensive laboratory analysis of rotational spectra. These constants can be used to predict transition frequencies that were not measured in the laboratory very precisely. Aims. We present an experimental study and a theoretical analysis of two 18O-methyl formate isotopologues, which were subsequently detected for the first time in Orion KL. Methods. The experimental spectra of both methyl formate isotopologues recorded in the microwave and sub-mm range from 1 to 660 GHz. Both spectra were analysed by using the rho-axis method (RAM) which takes into account the CH3 internal rotation. Results. We obtained spectroscopic constants of both 18O- methyl formate with high accuracy. Thousands of transitions were assigned and others predicted, which allowed us to detect both species in the IRAM 30 m line survey of Orion KL. ; M.C. acknowledges the financial support provided by the Andalusian Government (Spain) project number P07-FQM-03014. He also thanks Universite Paris 12 for inviting him. J.C. and B.T. thank Spanish MICINN for support under grants AYA2006-14786, AYA2009-07304 and the CONSOLIDER program "ASTROMOL" CSD2009-00038. This work was supported by the Centre National d'Etudes Spatiales (CNES) and the Action sur Projets de l'INSU, "Physique et Chimie du Milieu Interstellaire". This work was also done under the ANR-08-BLAN-0054.

22 pags., 27 figs., 6 tabs. ; Context. Yebes 40 m radio telescope is the main and largest observing instrument at Yebes Observatory and is devoted to very long baseline interferometry (VLBI) and single-dish observations since 2010. It has been covering frequency bands between 2 GHz and 90 GHz in discontinuous and narrow windows in most cases in order to match the current needs of the European VLBI Network (EVN) and the Global Millimeter VLBI Array (GMVA). Aims. The Nanocosmos project, a European Union-funded synergy grant, has enabled an increase in the instantaneous frequency coverage of the Yebes 40 m radio telescope, making it possible to observe many molecular transitions with single tunings in single-dish mode. This reduces the observing time and maximises the output from the telescope. Methods. We present technical specifications of the recently installed 31.5-50 GHz (Q band) and 72-90.5 GHz (W band) receivers along with the main characteristics of the telescope at these frequency ranges. We observed IRC+10216, CRL 2688, and CRL 618, which harbour a rich molecular chemistry, to demonstrate the capabilities of the new instrumentation for spectral observations in single-dish mode. Results. Our results show the high sensitivity of the telescope in the Q band. The spectrum of IRC+10126 offers an unprecedented signal-to-noise ratio for this source in this band. On the other hand, the spectrum normalised by the continuum flux towards CRL 618 in the W band demonstrates that the 40 m radio telescope produces comparable results to those from the IRAM 30 m radio telescope, although with a lower sensitivity. The new receivers fulfil one of the main goals of Nanocosmos and open up the possibility to study the spectrum of different astrophysical media with unprecedented sensitivity. ; The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC-SyG-2013 Grant Agreement No. 610256 Nanocosmos. Part of this work was supported by Programa operativo pluriregional de España, YDALGO. The observations mentioned in this article have been done under commissioning time and within projects 19A010 and 20A017. The Yebes 40m radio telescope belongs to Instituto Geográfico Nacional (IGN).

22 pags., 27 figs., 6 tabs. ; Context. Yebes 40 m radio telescope is the main and largest observing instrument at Yebes Observatory and is devoted to very long baseline interferometry (VLBI) and single-dish observations since 2010. It has been covering frequency bands between 2 GHz and 90 GHz in discontinuous and narrow windows in most cases in order to match the current needs of the European VLBI Network (EVN) and the Global Millimeter VLBI Array (GMVA). Aims. The Nanocosmos project, a European Union-funded synergy grant, has enabled an increase in the instantaneous frequency coverage of the Yebes 40 m radio telescope, making it possible to observe many molecular transitions with single tunings in single-dish mode. This reduces the observing time and maximises the output from the telescope. Methods. We present technical specifications of the recently installed 31.5-50 GHz (Q band) and 72-90.5 GHz (W band) receivers along with the main characteristics of the telescope at these frequency ranges. We observed IRC+10216, CRL 2688, and CRL 618, which harbour a rich molecular chemistry, to demonstrate the capabilities of the new instrumentation for spectral observations in single-dish mode. Results. Our results show the high sensitivity of the telescope in the Q band. The spectrum of IRC+10126 offers an unprecedented signal-to-noise ratio for this source in this band. On the other hand, the spectrum normalised by the continuum flux towards CRL 618 in the W band demonstrates that the 40 m radio telescope produces comparable results to those from the IRAM 30 m radio telescope, although with a lower sensitivity. The new receivers fulfil one of the main goals of Nanocosmos and open up the possibility to study the spectrum of different astrophysical media with unprecedented sensitivity. ; The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC-SyG-2013 Grant Agreement No. 610256 Nanocosmos. Part of this work was supported by Programa operativo pluriregional de España, YDALGO. The observations mentioned in this article have been done under commissioning time and within projects 19A010 and 20A017. The Yebes 40m radio telescope belongs to Instituto Geográfico Nacional (IGN).

CONTEXT: Yebes 40m radio telescope is the main and largest observing instrument at Yebes Observatory and it is devoted to Very Long Baseline Interferometry (VLBI) and single dish observations since 2010. It has been covering frequency bands between 2 GHz and 90 GHz in discontinuous and narrow windows in most of the cases, to match the current needs of the European VLBI Network (EVN) and the Global Millimeter VLBI Array (GMVA). AIMS: Nanocosmos project, a European Union funded synergy grant, opened the possibility to increase the instantaneous frequency coverage to observe many molecular transitions with single tunnings in single dish mode. This reduces the observing time and maximises the output from the telescope. METHODS: We present the technical specifications of the recently installed 31.5 – 50GHz (Q band) and 72 – 90.5 GHz (W band) receivers along with the main characteristics of the telescope at these frequency ranges. We have observed IRC+10216, CRL 2688 and CRL 618, which harbour a rich molecular chemistry, to demonstrate the capabilities of the new instrumentation for spectral observations in single dish mode. RESULTS: The results show the high sensitivity of the telescope in the Q band. The spectrum of IRC+10126 offers a signal to noise ratio never seen before for this source in this band. On the other hand, the spectrum normalised by the continuum flux towards CRL 618 in the W band demonstrates that the 40 m radio telescope produces comparable results to those from the IRAM 30 m radio telescope, although with a smaller sensitivity. The new receivers fulfil one of the main goals of Nanocosmos and open the possibility to study the spectrum of different astrophysical media with unprecedented sensitivity.

21 pags., 16 figs., 7 tabs., 2 apps. ; Context. Sulphur is one of the most abundant elements in the Universe. Surprisingly, sulphuretted molecules are not as abundant as expected in the interstellar medium and the identity of the main sulphur reservoir is still an open question. Aims. Our goal is to investigate the H2S chemistry in dark clouds, as this stable molecule is a potential sulphur reservoir. Methods. Using millimeter observations of CS, SO, H2S, and their isotopologues, we determine the physical conditions and H2S abundances along the cores TMC 1-C, TMC 1-CP, and Barnard 1b. The gas-grain model NAUTILUS is used to model the sulphur chemistry and explore the impact of photo-desorption and chemical desorption on the H2S abundance. Results. Our modeling shows that chemical desorption is the main source of gas-phase H2S in dark cores. The measured H2S abundance can only be fitted if we assume that the chemical desorption rate decreases by more than a factor of 10 when nH > 2 × 104. This change in the desorption rate is consistent with the formation of thick H2O and CO ice mantles on grain surfaces. The observed SO and H2S abundances are in good agreement with our predictions adopting an undepleted value of the sulphur abundance. However, the CS abundance is overestimated by a factor of 5-10. Along the three cores, atomic S is predicted to be the main sulphur reservoir. Conclusions. The gaseous H2S abundance is well reproduced, assuming undepleted sulphur abundance and chemical desorption as the main source of H2S. The behavior of the observed H2S abundance suggests a changing desorption efficiency, which would probe the snowline in these cold cores. Our model, however, highly overestimates the observed gas-phase CS abundance. Given the uncertainty in the sulphur chemistry, we can only conclude that our data are consistent with a cosmic elemental S abundance with an uncertainty of a factor of 10. ; We thank the Spanish MINECO for funding support from AYA2016-75066-C2-1/2-P, AYA2017-85111P, and ERC under ERC-2013-SyG, G. A. 610256 NANOCOSMOS. JM acknowledges the support of ERC-2015-STG No. 679852 RADFEEDBACK. S.P.T.M. acknowledge to the European Union's Horizon 2020 research and innovation program for funding support given under grant agreement No 639459 (PROMISE).