Suchergebnisse

This research received funding from the postdoctoral fellowships programme Beatriu de Pinós (2018 BP 00146), funded by the Secretary of Universities and Research (Governement of Catalonia) and by Horizon 2020 programme of research and innovation of the European Union under the Marie Skłodowska-Curie grant agreement No 801370. ; A functionalized silicon micromonolith of 7 mm in diameter and 210 μm-thick was evaluated for the production of hydrogen from the steam reforming (SR) of various fuels, containing different functional groups, such as ethanol, acetic acid, 2-propanol, acetone, and 2-methoxyethanol. The micromonolith consisted of 2 million regular channels of 3.3 μm in diameter, which were coated with a 100-nm RhPd/CeO2 catalytic layer. The catalytic activity was tested at temperatures between 823 and 1023 K, using overstoichiometric steam-to-carbon ratios and operating at contact times between 0.005 and 0.009 s. The best performance was obtained for the 2-methoxyethanol SR tests, where 53% H2 selectivity was recorded. A remarkable hydrogen production normalized by reactor volume of 110 LNH2·mL2-methoxyethanol, liquid−1 cm−3Reactor was recorded, leading to comparable H2 yields to those obtained with a conventional monolith coated with the same RhPd/CeO2 catalyst, owing to the large contact area. After more than 80 h under reaction conditions, the micromonolith was characterized by SEM and TEM. SEM analyses showed that no channels were blocked due to carbon deposition nor detached CeO2 layers were found. These results demonstrate the feasibility of using catalytic Si micromonoliths as microreformers to generate hydrogen from the SR of different fuels to power portable fuel cells. ; Postprint (author's final draft)

K2-18 is a nearby M2.5 dwarf, located at 34 pc and hosting a transiting planet that was first discovered by the K2 mission and later confirmed with Spitzer Space Telescope observations. With a radius of ∼2 R and an orbital period of ∼33 days, the planet lies in the temperate zone of its host star and receives stellar irradiation similar to that of Earth. Here we perform radial velocity follow-up observations with the visual channel of CARMENES with the goal of determining the mass and density of the planet. We measure a planetary semi-amplitude of K ∼ 3.5 and a mass of M ∼ 9 M , yielding a bulk density around . This indicates a low-mass planet with a composition consistent with a solid core and a volatile-rich envelope. A signal at 9 days was recently reported using radial velocity measurements taken with the HARPS spectrograph. This was interpreted as being due to a second planet. We see a weaker, time- and wavelength-dependent signal in the CARMENES data set and thus favor stellar activity for its origin. K2-18 b joins the growing group of low-mass planets detected in the temperate zone of M dwarfs. The brightness of the host star in the near-infrared makes the system a good target for detailed atmospheric studies with the James Webb Space Telescope.K2-18 is a nearby M2.5 dwarf, located at 34 pc and hosting a transiting planet that was first discovered by the K2 mission and later confirmed with Spitzer Space Telescope observations. With a radius of similar to 2 R-circle plus and an orbital period of similar to 33 days, the planet lies in the temperate zone of its host star and receives stellar irradiation similar to that of Earth. Here we perform radial velocity follow-up observations with the visual channel of CARMENES with the goal of determining the mass and density of the planet. We measure a planetary semi-amplitude of K-b similar to 3.5 m s(-1). and a mass of M-b similar to 9 M-circle plus, yielding a bulk density around rho(b) similar to 4 g cm(-3). This indicates a low-mass planet with a composition consistent with a solid core and a volatile-rich envelope. A signal at 9 days was recently reported using radial velocity measurements taken with the HARPS spectrograph. This was interpreted as being due to a second planet. We see a weaker, time-and wavelength-dependent signal in the CARMENES data set and thus favor stellar activity for its origin. K2-18 b joins the growing group of low-mass planets detected in the temperate zone of M dwarfs. The brightness of the host star in the near-infrared makes the system a good target for detailed atmospheric studies with the James Webb Space Telescope.© 2018. The American Astronomical Society. ; CARMENES is an instrument for the Centro Astronomico Hispano-Aleman de Calar Alto (CAHA, Almeria, Spain). CARMENES is funded by the German Max-Planck-Gesellschaft (MPG), the Spanish Consejo Superior de Investigaciones Cientificas (CSIC), the European Union through FEDER/ERF FICTS-2011-02 funds, and the members of the CARMENES Consortium (Max-Planck-Institut fur Astronomie, Instituto de Astrofisica de Andalucia, Landessternwarte Konigstuhl, Institut de Ciencies de l'Espai, Insitut fur Astrophysik Gottingen, Universidad Complutense de Madrid, Thuringer Landessternwarte Tautenburg, Instituto de Astrofisica de Canarias, Hamburger Sternwarte, Centro de Astrobiologia, and Centro Astronomico Hispano-Aleman), with additional contributions by the Spanish Ministry of Economy, the German Science Foundation (DFG), the states of Baden-Wurttemberg and Niedersachsen, and the Junta de Andalucia. P.S. would like to thank Christoph Mordasini for his helpful comments on an early draft and Sudeshna Boro-Saikia for her help on calculating the calcium indices of the HARPS data set. I.R. and J.C.M. acknowledge support by the Spanish Ministry of Economy and Competitiveness (MINECO) and the Fondo Europeo de Desarrollo Regional (FEDER) through grant ESP2016-80435-C2-1-R, as well as the support of the Generalitat de Catalunya/CERCA program. A.P.H. acknowledges the support of the Deutsche Forschungsgemeinschaft (DFG) grant HA 3279/11-1. J.A.C., P.J.A. and D.M. acknowledge support by the Spanish Ministry of Economy and Competitiveness (MINECO) from projects AYA2016-79425-C3-1, 2, 3-P. V.J.S.B. is supported by program AYA2015-69350-C3-2-P from Spanish Ministry of Economy and Competitiveness (MINECO). We thank the anonymous referee for useful comments that improved the paper.