Petroleum source rocks of western and central Africa : the examples of the marine Tarfaya Basin, Morocco and the continental Congo Basin, Democratic Republic of Congo
This study comprises newly collected organic geochemical and petrological data on quality, quantity, maturity as well as the depositional environment of various organic matter-rich stratigraphic units in Morocco and the Central Congo Basin, DRC. In addition, 1D modeling was carried out for one locality in northern Morocco (Aït Moussa) and for two wells from the Central Congo Basin to obtain information on burial thermal and maturation history. For the Aït Moussa model, specific bulk kinetic parameters were used to evaluate the petroleum generation and timing. Paleozoic, Mesozoic and Cenozoic sediments were investigated from the Tarfaya Basin, southern part of Morocco/Western Sahara. Based on Corg measurements, samples with Corg >0.4 %, especially Late Cretaceous and Eocene sedimentswere considered for further geochemical and petrological analysis. Rock-Eval pyrolysis and biomarker assignment indicate a mixture of kerogen type I/II with an excellent petroleum generation potential of the Late Cretaceous and Eocene samples. More detailed analysis of Coniacian, and Late Turonian samples from a newly drilled well (Tarfaya Sondage No.2) in the Tarfaya Basin support the latter data. In contrast to the terrestrial influenced Santonian outcrop samples Coniacian and Santonian samples of Tarfaya Sondage No.2 revealed marine organic matter with a higher Corg content and a better quality of the organic matter, represented by alginite. Vitrinite reflectance measurements and various sterane and hopane ratios , as well as Tmax values of Rock-Eval pyrolysis indicate an early mature to immature range of the organic matter. Sulphur contents and Corg/TS support the theory of mainly oxygen-depleted waters, but it is still ambiguous whether the bottom waters were permanently anoxic or rather oxygen-deficient. Although these investigated source rocks of Late Cretaceous and Eocene age are excellent with respect to organic richness, kerogen quality and thickness, their low maturity poses a major problem for petroleum exploration. ...