Article(electronic)#11983
Vibrational analysis of chlorine dioxide in the ground state, electrically excited state and ionic state
In: Bulletin de la Classe des Sciences de l'Académie Royale de Sciences, des Lettres et des Beaux-Arts de Belgique, Volume 69, Issue 1, p. 304-309
Based on the normal coordinate theory, the vibrational analysis of the ground state (Bt), the electronically excited state (A2) and singly ionised state (A,) of ClO2 has been carried out and the force constants corresponding to these three states have been evaluated by kinetic constants method employing the general valence force field. These force constants have been used to calculate the mean square amplitudes of vibration, Coriolis Coupling Coefficients and Centrifugal distortion constants of ClO2 in these three states.