Building zeolites from precrystallized units: nanoscale architecture

Abstract

15330 15353 57 47 ; S Moliner, M., Martínez, C., & Corma, A. (2015). Multiporige Zeolithe: Synthese und Anwendungen bei der Katalyse. Angewandte Chemie, 127(12), 3630-3649. doi:10.1002/ange.201406344 Moliner, M., Rey, F., & Corma, A. (2013). Rationales Design von effizienten organischen strukturdirigierenden Reagentien für die Zeolithsynthese. Angewandte Chemie, 125(52), 14124-14134. doi:10.1002/ange.201304713 Jiang, J., Yu, J., & Corma, A. (2010). Zeolithe mit sehr großen Poren als Bindeglied zwischen mikro- und mesoporösen Strukturen. Angewandte Chemie, 122(18), 3186-3212. doi:10.1002/ange.200904016 C. T.Kresge W. J.Roth U.S. Patent 5266541 1993. S. I.Zones US 4544538 1985. T. V.Whittam US Pat 4397825 1983. Corma, A., Puche, M., Rey, F., Sankar, G., & Teat, S. J. (2003). Angewandte Chemie, 115(10), 1188-1191. doi:10.1002/ange.200390275 A. W.Burton WO2014/099261 2014; ; D.Xie WO2016/122724 2016. ; Sun, J., Bonneau, C., Cantín, Á., Corma, A., Díaz-Cabañas, M. J., Moliner, M., … Zou, X. (2009). The ITQ-37 mesoporous chiral zeolite. Nature, 458(7242), 1154-1157. doi:10.1038/nature07957 ; S. I.Zones Y.Nakagawa S. T.Evans G. S.Lee US 5958370 1999; ; This is the peer reviewed version of the following article: Angew. Chem. Int. Ed. 2018, 57, 15330 15353, which has been published in final form at https://doi.org/10.1002/anie.201711422. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. [EN] Since the early reports by Barrer in the 1940s on converting natural minerals into synthetic zeolites, the use of precrystallized zeolites as crucial inorganic directing agents to synthesize other crystalline zeolites with improved physicochemical properties has become a very important research field, allowing the design, particularly in recent years, of new industrial catalysts. This Review highlights how the presence of some crystalline fragments in the synthesis media, such as small secondary building units (SBUs) or layered substructures, not ...