Women's Organizations and Social Capital to Reduce Prevalence of Child Malnutrition in Papua New Guinea
In: Oxford development studies, Band 36, Heft 2, S. 209-233
ISSN: 1469-9966
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In: Oxford development studies, Band 36, Heft 2, S. 209-233
ISSN: 1469-9966
ScMN2-type (M = V, Nb, Ta) phases are layered materials that have been experimentally reported for M = Ta and Nb, but their high-pressure properties have not been studied. Here, we have used first-principles calculations to study their thermodynamic stability, elastic and electronic properties at high-pressure. We have used density functional theory to calculate the formation enthalpy relative to the competing binary phases, electronic density of states and elastic constants (c(ij)), bulk (B), shear (G) and Youngs (E) modulus as the pressure is varied from 0 to 150 GPa. Our results show that when the pressure increases from 0 to 150 GPa, elastic constants, bulk, shear and elastic moduli increase in the range 53-216% for ScTaN2, 72-286% for ScNbN2, and 61-317% for ScVN2. ; Funding Agencies|Swedish Research Council (VR) [2016-03365]; Knut and Alice Wallenberg Foundation through the Wallenberg Academy Fellows program; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [2009 00971]
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ScMN2-type (M = V, Nb, Ta) phases are layered materials that have been experimentally reported for M = Ta and Nb. They are narrow-bandgap semiconductors with potentially interesting thermoelectric properties. Point defects such as dopants and vacancies largely affect these properties, motivating the need to investigate these effects. In particular, asymmetric peak features in the density of states (DOS) close to the highest occupied state is expected to increase the Seebeck coefficient. Here, we used first principles calculations to study the effects of one vacancy or one C, O, or F dopant on the DOS of the ScMN2 phases. We used density functional theory to calculate formation energy and the density of states when a point defect is introduced in the structures. In the DOS, asymmetric peak features close to the highest occupied state were found as a result of having a vacancy in all three phases. Furthermore, one C dopant in ScTaN2, ScNbN2, and ScVN2 implies a shift of the highest occupied state into the valence band, while one O or F dopant causes a shift of the highest occupied state into the conduction band. ; Funding agencies: Swedish Research Council (VR)Swedish Research Council [2016-03365]; Knut and Alice Wallenberg Foundation through the Wallenberg Academy Fellows program; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping U
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The last few years have seen a rise in the interest in early transition-metal and rare-earth nitrides, primarily based on ScN and CrN, for energy harvesting by thermoelectricity and piezoelectricity. This is because of a number of important advances, among those the discoveries of exceptionally high piezoelectric coupling coefficient in (Sc,Al)N alloys and of high thermoelectric power factors of ScN-based and CrN-based thin films. These materials also constitute well-defined model systems for investigating thermodynamics of mixing for alloying and nanostructural design for optimization of phase stability and band structure. These features have implications for and can be used for tailoring of thermoelectric and piezoelectric properties. In this highlight article, we review the ScN-and CrN-based transition-metal nitrides for thermoelectrics, and drawing parallels with piezoelectricity. We further discuss these materials as a models systems for general strategies for tailoring of thermoelectric properties by integrated theoretical-experimental approaches. ; Funding Agencies|European Research Council under the European Communitys Seventh Framework Programme/ERC [335383]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009 00971]; Swedish Foundation for Strategic Research (SSF) through the Future Research Leaders 5 program; Swedish Research Council (VR) [621-2012-4430, 621-2011-4417, 330-2014-6336]
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In: The journal of development studies, Band 43, Heft 3, S. 456-489
ISSN: 1743-9140
In: The journal of development studies: JDS, Band 43, Heft 3, S. 456-489
ISSN: 0022-0388
World Affairs Online
The effect of the wet-cleaning process using solvents and detergent on the surface chemistry of MgO(001) substrate for film deposition was investigated. Six different wet-cleaning processes using solvent and detergent were compared. The effect on film growth was studied by the example system ScN. The surface chemistry of the cleaned surface was studied by x-ray photoelectron spectroscopy and the film/substrate interface after film growth was investigated by time-of-flight secondary ion mass spectroscopy. The surface composition is dependent on the wet-cleaning process. Sonication in a detergent before the solvents yield a pure oxide surface compared to hydroxide/carbonate contaminated surface for all the other processes. An annealing step is efficient for the removal of carbon contamination as well as most of the hydroxide or carbonates. The study of the film/substrate interface revealed that the wet-cleaning process significantly affects the final interface and film quality. The substrate cleaned with detergent followed by solvent cleaning exhibited the cleanest surface of the substrate before annealing, after annealing, in addition to the sharpest film/substrate interface. (C) 2017 American Vacuum Society. ; Funding Agencies|European Research Council under the European Communitys Seventh Framework Programme (FP) [335383]; Knut and Alice Wallenberg Foundation through the Wallenberg Academy Fellows program; Swedish Research Council (VR) [6212012-4430]; Swedish Foundation for Strategic Research (SSF) through the Future Research Leaders 5 program; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Link_oping University [2009-00971]
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Inherently and artificially layered materials are commonly investigated both for fundamental scientific purposes and for technological application. When a layered material is thinned or delaminated to its physical limits, a two-dimensional (2D) material is formed and exhibits novel properties compared to its bulk parent phase. The complex layered phases known as MAX phases (where M = early transition metal, A = A-group element, e.g. Al or Si, and X = C or N) are an exciting model system for materials design and the understanding of process-structure-property relationships. When the A layers are selectively etched from the MAX phases, a new type of 2D material is formed, named MXene to emphasize the relation to the MAX phases and the parallel with graphene. Since their discovery in 2011, MXenes have rapidly become established as a novel class of 2D materials with remarkable possibilities for composition variations and property tuning. This article gives a brief overview of MAX phases and MXene from a thin-film perspective, reviewing theory, characterization by electron microscopy, properties and how these are affected by the change in dimensionality, and outstanding challenges. ; Funding Agencies|European Research Council under the European Communitys Seventh Framework Programme (FP) ERC [335383, 258509]; knut and Alice Wallenberg Foundation through the Wallenberg Academy Fellows program; electron microscopy laboratory in Linkoping; Swedish Research Council (VR) [621-2012-4430, 6212012-4425, 642-2013-8020, 621-2012-4359, 622-2008405]; Swedish Foundation for Strategic Research (SSF) through the Synergy Grant FUNCASE; Future Research Leaders 5 program (PE); Swedish Government-Strategic Research Area in Materials Science on Functional Materials at Linkoping University [2009-00971]; Research Infrastructure Fellow program (POAP)
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The development of fully-inorganic thin flexible materials is important for flexible thermoelectric applications in a wide temperature range, such as harvesting power from hot curved surfaces (e.g. hot pipes). Here, we investigate the thermoelectric properties of a series of ZnO:Ga,Al thin films with varying dopant concentration deposited on flexible mica substrate by atmospheric pressure metalorganic chemical vapor deposition. The films are bendable, while sustaining the high power factor, above 1 x 10(-4)Wm(-1)K(-2) for singly doped Zn0.99Ga0.01O film in a wide temperature range, from room temperature to 400 degrees C. IMPACT STATEMENTFor the first time we demonstrate here that ZnO-film-on-mica can be a promising n-type candidate for fully-inorganic flexible thermoelectrics, especially, for applications at elevated temperatures [GRAPHICS] ; Funding Agencies|European Research Council (ERC) under the European Community [335383]; Swedish Research Council (VR) [2016-03365]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [SFO-Mat-LiU 2009 00971]; Knut and Alice Wallenberg foundation through the Academy Fellow program; Swedish Foundation for Strategic Research (SSF) through the Future Research Leaders 5 program; Swedish Research Council (VR) Marie Sklodowska Curie International Career Grant [2015-00679]; AForsk [14-517]
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Scandium nitride has recently gained interest as a prospective compound for thermoelectric applications due to its high Seebeck coefficient. However, ScN also has a relatively high thermal conductivity, which limits its thermoelectric efficiency and figure of merit (zT). These properties motivate a search for other semiconductor materials that share the electronic structure features of ScN, but which have a lower thermal conductivity. Thus, the focus of our study is to predict the existence and stability of such materials among inherently layered equivalent ternaries that incorporate heavier atoms for enhanced phonon scattering and to calculate their thermoelectric properties. Using density functional theory calculations, the phase stability of TiMgN2, ZrMgN2 and HfMgN2 compounds has been calculated. From the computationally predicted phase diagrams for these materials, we conclude that all three compounds are stable in these stoichiometries. The stable compounds may have one of two competing crystal structures: a monoclinic structure (LiUN2 prototype) or a trigonal superstructure (NaCrS2 prototype; RmH). The band structure for the two competing structures for each ternary is also calculated and predicts semiconducting behavior for all three compounds in the NaCrS2 crystal structure with an indirect band gap and semiconducting behavior for ZrMgN2 and HfMgN2 in the monoclinic crystal structure with a direct band gap. Seebeck coefficient and power factors are also predicted, showing that all three compounds in both the NaCrS2 and the LiUN2 structures have large Seebeck coefficients. The predicted stability of these compounds suggests that they can be synthesized by, e.g., physical vapor deposition. ; Funding Agencies|European Research Council under the European Communitys Seventh Framework Programme (FP)/ERC [335383]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009 00971]; Swedish Foundation for Strategic Research (SSF) through the Future Research Leaders 5 and 6 programs; Knut and Alice Wallenberg foundation through the Academy Fellow program; Swedish Research Council (VR) [621-2012-4430, 2016-03365]; Swedish Research Council (VR) through International Career Grant [330-2014-6336]; Marie Sklodowska Curie Actions, Cofund [INCA 600398]; VR Grant [2016-04810]; Swedish e-Science Research Centre (SeRC)
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Nanocomposite transition metal carbide/amorphous carbon coatings (Me-C/a-C) deposited by magnetron sputtering have excellent electrical contact properties. The contact resistance can be as low as that of noble metal coatings, although it is known to vary by several orders of magnitude depending on the deposition conditions. We have investigated a nanocrystalline niobium carbide/amorphous carbon (NbC (x) /a-C:H) model system aiming to clarify factors affecting the contact resistance for this group of contact materials. For the first time, the surface chemistry is systematically studied, by angle-resolved X-ray photoelectron spectroscopy, and in extension how it can explain the contact resistance. The coatings presented a mean oxide thickness of about 1 nm, which could be grown to 8 nm by annealing. Remarkably, the contact resistances covered four orders of magnitude and were found to be exponentially dependent on the mean oxide thickness. Moreover, there is an optimum in the amount of a-C:H phase where the contact resistance drops very significantly and it is thus important to not only consider the mean oxide thickness. To explain the results, a model relying on surface chemistry and contact mechanics is presented. The lowest contact resistance of a nanocomposite matched that of a gold coating at 1 N load (vs. gold), and such performance has previously not been demonstrated for similar nanocomposite materials, highlighting their useful properties for electrical contact applications. ; Funding Agencies|Swedish Foundation; Swedish Governmental Agency for Innovation Systems; Swedish Research Council [VR 2011-3492]; Synergy Grant FUNCASE, Functional Carbides and Advanced Surface Engineering
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Hybrids between biopolymeric materials and low-cost conductive carbon-based materials are interesting materials for applications in electronics, potentially reducing the need for materials that generate environmentally harmful electronic waste. Herein we investigate a scalable ball-milling method to form graphene nanoplatelets (GNPs) by milling graphite flakes with aqueous dispersions of proteins or protein nanofibrils (PNFs). Aqueous GNP dispersions with high concentrations (up to 3.2 mg mL(-1)) are obtained under appropriate conditions. The PNFs/proteins help to exfoliate graphite and stabilize the resulting GNP dispersions by electrostatic repulsion. PNFs are prepared from hen egg white lysozyme (HEWL) and beta-lactoglobulin (BLG). The GNP dispersions can be processed into free-standing films having an electrical conductivity of up to 110 S m(-1). Alternatively, the GNP dispersions can be drop-cast on PET substrates, resulting in mechanically flexible films having an electrical conductivity of up to 65 S m(-1). The drop-cast films are investigated regarding their thermoelectric properties, having Seebeck coefficients of about 50 mu V K-1. By annealing drop-cast films and thus carbonizing residual PNFs, an increase of electrical conductivity, coupled with a modest decrease in Seebeck coefficient, is obtained resulting in materials displaying power factors of up to 4.6 mu W m(-1) K-2. ; Funding Agencies|China Scholarship CouncilChina Scholarship Council; FormasSwedish Research Council Formas [2019-00679]; COST (European Cooperation in Science and Technology)European Cooperation in Science and Technology (COST) [CA18112]; Knut and Alice Wallenberg Foundation through the Wallenberg Academy Fellows program; Swedish Energy AgencySwedish Energy Agency [46519-1]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009 00971]
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ScMN2-type (M = V, Nb, Ta) phases are layered materials that have been experimentally reported for M = Ta and Nb, but they have up to now not been much studied. However, based on the properties of binary ScN and its alloys, it is reasonable to expect these phases to be of relevance in a range of applications, including thermoelectrics. Here, we have used first-principles calculations to study their thermodynamic stability, elastic, thermoelectric and electronic properties. We have used density functional theory to calculate lattice parameters, the mixing enthalpy of formation and electronic density of states as well as the thermoelectric properties and elastic constants (cij), bulk (B), shear (G) and Young's (E) modulus, which were compared with available experimental data. Our results indicate that the considered systems are thermodynamically and elastically stable and that all are semiconductors with small band gaps. All three materials display anisotropic thermoelectric properties and indicate the possibility to tune these properties by doping. In particular, ScVN2, featuring the largest band gap exhibits a particularly large and strongly doping-sensitive Seebeck coefficient. ; Funding agencies: Swedish Research Council (VR) [2016-03365]; Knut and AliceWallenberg Foundation through the Academy Fellows Program; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [2009 00971]; European Res
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Thermoelectric properties of chromium nitride (CrN)-based films grown on c-plane sapphire by dc reactive magnetron sputtering were investigated. In this work, aluminum doping was introduced in CrN (degenerate n-type semiconductor) by co-deposition. Under the present deposition conditions, over-stoichiometry in nitrogen (CrN1+delta) rock-salt structure is obtained. A p-type conduction is observed with nitrogen-rich CrN combined with aluminum doping. The Cr0.96Al0.04N1.17 film exhibited a high Seebeck coefficient and a sufficient power factor at 300 degrees C. These results are a starting point for designing p-type/n-type thermoelectric materials based on chromium nitride films, which are cheap and routinely grown on the industrial scale. (C) 2018 The Japan Society of Applied Physics ; Funding Agencies|European Research Council under the European Communitys Seventh Framework Programme (FP)/ERC [335383]; Swedish Foundation for Strategic Research (SSF) through the Future Research Leaders 5 program; Swedish Research Council (VR) [621-2012-4430, 2016-03365]; Knut and Alice Wallenberg Foundation through the Wallenberg Academy Fellows program; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [2009 00971]; M.ERA-NET project MC2 - French ANR program [ANR-13-MERA-0002-02]; CTEC project [1305-00002B]
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MXenes, transition metal carbides and/or nitrides, that are synthesized from the top down by etching of their 3D parent layered solids, the MAX phases, are the latest family of the two-dimensional solids discovered. When the A layers - mostly Al - are etched they are replaced by surface terminations, Tz mainly comprised of O-, OH- and F-terminations. One of the few techniques capable of quantifying these surface terminations is X-ray photo-electron spectroscopy, XPS. Herein, we undertook an XPS study of the out-of-plane ordered MXenes, Mo2TiC2Tz and Mo2Ti2C3Tz, in both multilayered, ML, cold pressed and delaminated thin film forms. The harsh conditions needed to etch these MAX phases into MLs, results in their partial oxidation. The hydroxide used to delaminate the MLs results in further oxidation and a reduction in the F-content. In all cases, etching resulted in a decrease in the Ti to Mo ratio implying that the former atoms are selectively etched. In all but the ML Mo2TiC2Tz case, the Mo to C ratio was also reduced. It follows that the loss of Ti also results in the loss of C atoms. Again with the exception of the ML Mo2Ti2C3Tz case, the number of termination moles per formula unit, z, was amp;gt; 2, which is energetically unfavorable and thus unlikely. However, if one assumes that not all of the O signal is coming from terminations but rather from O atoms that replace C atoms in the MX blocks, then z similar to 2. This work is an important step in quantifying and understanding the effects of etching on terminations and structure in these Mo and Ti-based MXenes. ; Funding Agencies|Swedish Research CouncilSwedish Research Council [621-2014-4890, 642-2013-8020]; Knut and Alice Wallenberg Foundation (KAW)Knut & Alice Wallenberg Foundation [KAW 2015.0043]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009-00971]; Swedish Foundation for Strategic Research (SSF)Swedish Foundation for Strategic Research [EM16-0004]
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